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Award ID contains: 1800110

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  1. ; ; ; ; ; (, Inorganic Chemistry)
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  2. ; (, Journal of the American Chemical Society)
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  3. ; ; ; ; (, Chemical Communications)
    A tin-supported iron catalyst produces 5.9 turnovers of NH 3 from N 2 , using [Ph 2 NH 2 ]OTf as the acid and CoCp 2 * as the reductant. Two redox states of the Fe(N 2 ) adduct and an Fe silyldiazenido complex were characterized using X-ray crystallography along with NMR and Mössbauer spectroscopies. Density functional theory calculations reveal that the charge on the Sn center correlates strongly with both the polarization of the N 2 moiety and the charge on the distal N atom. 
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  4. ; ; ; ; (, Inorganic Chemistry)
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  5. ; ; ; ; ; ; ; ; ; ; et al (, Inorganic Chemistry)