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Characterizing the degree of disturbance in archaeological deposits is critically important for archaeologists assessing foraging strategies, environmental conditions, or behavior patterns of ancient human groups. Qualitative techniques (e.g. micromorphology analysis) have previously been applied to assess the degree of disturbance (age-mixing) in archaeological sites; however, quantitative dating of material in the sites provides a more robust assessment of potential age-mixing. Unfortunately, because of budget constraints, archaeologists are frequently forced to rely on few quantitative age dates for an assemblage, thus obfuscating the signal of age-mixing of the deposit. The development of an affordable and rapid carbonate-target accelerator mass spectrometry (AMS) radiocarbon ( 14 C) dating method provides a cost-effective way to retrieve more quantitative dates from carbonate material in archaeological assemblages to assess the degree of age-mixing in the deposit. This study tests this new technique and dates numerous harvested marine limpet shells from archaeological sites in the Canary Islands to determine whether there is multidecadal to multicentennial age-mixing. A total of 58 shells retrieved from six sites and three islands yielded uncalibrated radiocarbon ages ranging from 2265 ± 40 to 765 ± 35 BP, coinciding with the time of prehistoric human occupation in these islands. While most shells from the same stratum showed statistically equivalent ages, in some cases we detected age ranges that exceeded the imprecisions from analytical errors. This investigation is one of the first to quantitatively illustrate that shells retrieved from depth intervals without evident stratigraphic disturbance do not always contain contemporaneous remains and, therefore, dating each specimen is valuable for developing further paleoclimatic and paleoanthropological inferences. This study presents the first report of carbonate-target 14 C ages from archaeological shell middens, and suggests that this novel radiocarbon methodology can be applied to these sites, thus allowing the generation of a more comprehensive chronology. 

The Medieval Climate Anomaly (MCA; 900e1300 AD) was the most recent period of pre-industrial climatic warming in the northern hemisphere, and thus estimations of MCA signals can illuminate possible impacts of anthropogenic climate change. Current high-resolution MCA climate signals are restricted to mid- and high-latitude regions, which confounds inferences of how the MCA impacted some global/hemispheric climate mechanisms (e.g. North Atlantic Oscillation; NAO). To address this knowledge gap, we estimate seasonally-resolved sea surface temperatures (SSTs) from the oxygen isotope composition (d18O) of serially sampled Phorcus atratus shells from archaeological sites spanning the MCA in the Canary Islands. Twelve archaeological and six modern P. atratus shells were analyzed, and archaeological shells were dated using carbonate-target radiocarbon dating. SSTs were estimated using the published aragonite-water equilibrium fractionation equation. Modern shells showed a mean SST of 20.0 ± 1.5
C, with a seasonal amplitude of 5.3 ± 0.9
C. Archaeological shells exhibited a mean SST of 18.2 ± 0.7
C, with a mean seasonal amplitude of 5.5 ± 1.0
C. Thus, shells that span the MCA in the Canary Islands recorded SSTs that were significantly cooler than the modern (P < .05), contrasting with warming estimates and model predictions elsewhere in the Northern Hemisphere. We propose that the observed cooling resulted from increased upwelling in NW Africa due to a strengthening of the prevailing westerlies and coastal winds along the African shoreline. The intensified upwelling scenario during the MCA is partially supported by in-situ carbon isotope data (d13C) retrieved from the archaeological shells, which was compared to the d13C values of modern shells and dissolved inorganic carbon in the ambient seawater. These results are consistent with other low-latitude temperature/precipitation anomalies associated with a positive NAO mode, suggesting a transition to a positive NAO index during the middle and late MCA that possibly extended later into the 13th century AD.