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Dioxygen reactivity of a biomimetic [4Fe-4S] compound exhibits [4Fe-4S] to [2Fe-2S] cluster conversion

https://doi.org/10.1016/j.jinorgbio.2022.111714

Oakley, Kady M.; Lehane, Ryan L.; Zhao, Ziyi; Kim, Eunsuk (March 2022, Journal of Inorganic Biochemistry)

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The Biologically Relevant Coordination Chemistry of Iron and Nitric Oxide: Electronic Structure and Reactivity

https://doi.org/10.1021/acs.chemrev.1c00253

Lehnert, Nicolai; Kim, Eunsuk; Dong, Hai T.; Harland, Jill B.; Hunt, Andrew P.; Manickas, Elizabeth C.; Oakley, Kady M.; Pham, John; Reed, Garrett C.; Alfaro, Victor Sosa (December 2021, Chemical Reviews)
Controlled Protonation of [2Fe–2S] Leading to MitoNEET Analogues and Concurrent Cluster Modification

https://doi.org/10.1021/acs.inorgchem.1c02622

Oakley, Kady; Sterling, Kevin; Shearer, Jason; Kim, Eunsuk (November 2021, Inorganic Chemistry)

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Generation of H ₂ S from Thiol-Dependent NO Reactivity of Model [4Fe-4S] Cluster and Roussin’s Black Anion

https://doi.org/10.1021/acs.inorgchem.1c01328

Oakley, Kady M.; Zhao, Ziyi; Lehane, Ryan L.; Ma, Ji; Kim, Eunsuk (June 2021, Inorganic Chemistry)
null (Ed.)
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Reactivity of a biomimetic W( iv ) bis-dithiolene complex with CO ₂ leading to formate production and structural rearrangement

https://doi.org/10.1039/c9dt03906f

Seo, Junhyeok; Shearer, Jason; Williard, Paul G.; Kim, Eunsuk (December 2019, Dalton Transactions)

A mononuclear W( iv ) bis-dithiolene complex stabilized by an oxo ligand shows a reductive reactivity toward CO 2 , from which formate and a dinuclear W( v ) complex are generated. An unusual structural rearrangement was observed during the reaction. Structural and spectroscopic characterization for a novel triply bridged dinuclear W( v ) complex is reported.
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