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Dioxygen reactivity of a biomimetic [4Fe-4S] compound exhibits [4Fe-4S] to [2Fe-2S] cluster conversion

https://doi.org/10.1016/j.jinorgbio.2022.111714

Oakley, Kady M. ; Lehane, Ryan L. ; Zhao, Ziyi ; Kim, Eunsuk ( March 2022 , Journal of Inorganic Biochemistry)

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The Biologically Relevant Coordination Chemistry of Iron and Nitric Oxide: Electronic Structure and Reactivity

https://doi.org/10.1021/acs.chemrev.1c00253

Lehnert, Nicolai ; Kim, Eunsuk ; Dong, Hai T. ; Harland, Jill B. ; Hunt, Andrew P. ; Manickas, Elizabeth C. ; Oakley, Kady M. ; Pham, John ; Reed, Garrett C. ; Alfaro, Victor Sosa ( December 2021 , Chemical Reviews)
Controlled Protonation of [2Fe–2S] Leading to MitoNEET Analogues and Concurrent Cluster Modification

https://doi.org/10.1021/acs.inorgchem.1c02622

Oakley, Kady ; Sterling, Kevin ; Shearer, Jason ; Kim, Eunsuk ( November 2021 , Inorganic Chemistry)

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Generation of H 2 S from Thiol-Dependent NO Reactivity of Model [4Fe-4S] Cluster and Roussin’s Black Anion

https://doi.org/10.1021/acs.inorgchem.1c01328

Oakley, Kady M. ; Zhao, Ziyi ; Lehane, Ryan L. ; Ma, Ji ; Kim, Eunsuk ( June 2021 , Inorganic Chemistry)
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Reactivity of a biomimetic W( iv ) bis-dithiolene complex with CO 2 leading to formate production and structural rearrangement

https://doi.org/10.1039/c9dt03906f

Seo, Junhyeok ; Shearer, Jason ; Williard, Paul G. ; Kim, Eunsuk ( December 2019 , Dalton Transactions)

A mononuclear W( iv ) bis-dithiolene complex stabilized by an oxo ligand shows a reductive reactivity toward CO 2 , from which formate and a dinuclear W( v ) complex are generated. An unusual structural rearrangement was observed during the reaction. Structural and spectroscopic characterization for a novel triply bridged dinuclear W( v ) complex is reported.
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