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Ligand-Based Control of Nickel Catalysts: Switching Chemoselectivity from One-Electron to Two-Electron Pathways in Competing Reactions of 4-Halotetrahydropyrans

https://doi.org/10.1021/acs.orglett.2c01335

Thane, Taylor A. ; Jarvo, Elizabeth R. ( July 2022 , Organic Letters)

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Nickel-Catalyzed Domino Cross-Electrophile Coupling Dicarbofunctionalization Reaction To Afford Vinylcyclopropanes

https://doi.org/10.1021/acscatal.1c04235

Hewitt, Kirsten A. ; Xie, Pei-Pei ; Thane, Taylor A. ; Hirbawi, Nadia ; Zhang, Shuo-Qing ; Matus, Alissa C. ; Lucas, Erika L. ; Hong, Xin ; Jarvo, Elizabeth R. ( December 2021 , ACS Catalysis)

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Nickel-Catalyzed Kumada Cross-Coupling Reactions of Benzylic Sulfonamides

https://doi.org/10.3390/molecules26195947

Hewitt, Kirsten A. ; Herbert, Claire A. ; Matus, Alissa C. ; Jarvo, Elizabeth R. ( October 2021 , Molecules)

Herein, we report a Kumada cross-coupling reaction of benzylic sulfonamides. The scope of the transformation includes acyclic and cyclic sulfonamide precursors that cleanly produce highly substituted acyclic fragments. Preliminary data are consistent with a stereospecific mechanism that allows for a diastereoselective reaction.
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