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Selective adsorption of volatile organic compounds in metal-organic frameworks (MOFs)

https://doi.org/10.1016/j.ccr.2023.215119

Siu, Benjamin; Chowdhury, Aminur Rashid; Yan, Ziwen; Humphrey, Simon M; Hutter, Tanya (June 2023, Coordination Chemistry Reviews)

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Low-Valent Metal Ions as MOF Pillars: A New Route Toward Stable and Multifunctional MOFs

https://doi.org/10.1021/jacs.1c05564

Sikma, R. Eric; Katyal, Naman; Lee, Su-Kyung; Fryer, Joseph W.; Romero, Catherine G.; Emslie, Samuel K.; Taylor, Elinor L.; Lynch, Vincent M.; Chang, Jong-San; Henkelman, Graeme; et al (September 2021, Journal of the American Chemical Society)

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In situ formation and solid-state oxidation of a triselenane NSeN-pincer MOF

https://doi.org/10.1039/c9cc07851g

He, Shichao; Allemond, Laynee L.; Dunning, Samuel G.; Reynolds, Joseph E.; Lynch, Vincent M.; Humphrey, Simon M. (January 2020, Chemical Communications)

Controlled partial decomposition of 2-selenonicotinic acid in the presence of Co 2+ or Ni 2+ resulted in the in situ formation of an unusual MOF based on triselenane ligands (RSeSeSeR) coordinated to M 2+ centers as NSeN-pincers. Post-synthetic oxidation by treatment with aqueous H 2 O 2 facilitates its solid-state conversion into a RSeO 2 − molecular coordination complex, which was tracked via powder X-ray diffraction studies and by single-crystal structural resolution of the final product.
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