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The coldest Y spectral type brown dwarfs are similar in mass and temperature to cool and warm (∼200–400 K) giant exoplanets. We can therefore use their atmospheres as proxies for planetary atmospheres, testing our understanding of physics and chemistry for these complex, cool worlds. At these cold temperatures, their atmospheres are cold enough for water clouds to form, and chemical timescales increase, increasing the likelihood of disequilibrium chemistry compared to warmer classes of planets. JWST observations are revolutionizing the characterization of these worlds with high signal-to-noise, moderate-resolution near- and mid-infrared spectra. The spectra have been used to measure the abundances of prominent species, like water, methane, and ammonia; species that trace chemical reactions, like carbon monoxide; and even isotopologues of carbon monoxide and ammonia. Here, we present atmospheric retrieval results using both published fixed-slit (Guaranteed Time Observation program 1230) and new averaged time series observations (GO program 2327) of the coldest known Y dwarf, WISE 0855–0714 (using NIRSpec G395M spectra), which has an effective temperature of ∼264 K. We present a detection of deuterium in an atmosphere outside of the solar system via a relative measurement of deuterated methane (CH₃D) and standard methane. From this, we infer the D/H ratio of a substellar object outside the solar system for the first time. We also present a well-constrained part-per-billion abundance of phosphine (PH₃). We discuss our interpretation of these results and the implications for brown dwarf and giant exoplanet formation and evolution.

We present an atmospheric retrieval analysis on a set of young, cloudy, red L dwarfs—CWISER J124332.12+600126.2 (BD+60 1417B) and WISEP J004701.06+680352.1 (W0047)—using the Brewster retrieval framework. We also present the first elemental abundance measurements of the young K-dwarf (K0) host star, BD+60 1417, using high-resolution (R= 50,000) spectra taken with the Potsdam Echelle Polarimetric and Spectroscopic Instrument on the Large Binocular Telescope. In the complex cloudy L-dwarf regime the emergence of condensate cloud species complicates retrieval analysis when only near-infrared data are available. We find that for both L dwarfs in this work, despite testing three different thermal profile parameterizations we are unable to constrain reliable abundance measurements and thus the carbon-to-oxygen ratio. While we cannot conclude what the abundances are, we can conclude that the data strongly favor a cloud model over a cloudless model. We note that the difficulty in retrieval constraints persists regardless of the signal-to-noise ratio of the data examined (S/N ∼ 10 for CWISER BD+60 1417B and 40 for WISEP W0047). The results presented in this work provide valuable lessons about retrieving young, low-surface-gravity cloudy L dwarfs. This work provides continued evidence of missing information in models and the crucial need for JWST to guide and inform retrieval analysis in this regime.

We present the discovery of VHS J183135.58−551355.9 (hereafter VHS J1831−5513), an L/T transition dwarf identified as a result of its unusually red near-infrared colors (J−K_S= 3.633 ± 0.277 mag;J−W2 = 6.249 ± 0.245 mag) from the VISTA Hemisphere Survey and CatWISE2020 surveys. We obtain low-resolution near-infrared spectroscopy of VHS J1831−5513 using the Magellan Folded port InfraRed Echellette spectrograph to confirm its extremely red nature and assess features sensitive to surface gravity (i.e., youth). Its near-infrared spectrum shows multiple CH₄absorption features, indicating an exceptionally low effective temperature for its spectral type. Based on proper-motion measurements from CatWISE2020 and a photometric distance derived from itsK_s-band magnitude, we find that VHS J1831−5513 is a likely (∼85% probability) kinematic member of theβPictoris moving group. Future radial velocity and trigonometric parallax measurements will clarify such membership. Follow-up mid-infrared or higher-resolution near-infrared spectroscopy of this object will allow for further investigation as to the cause(s) of its redness, such as youth, clouds, and viewing geometry.

Beyond our Solar System, aurorae have been inferred from radio observations of isolated brown dwarfs^1,2. Within our Solar System, giant planets have auroral emission with signatures across the electromagnetic spectrum including infrared emission of H₃⁺and methane. Isolated brown dwarfs with auroral signatures in the radio have been searched for corresponding infrared features, but only null detections have been reported³. CWISEP J193518.59-154620.3. (W1935 for short) is an isolated brown dwarf with a temperature of approximately 482 K. Here we report James Webb Space Telescope observations of strong methane emission from W1935 at 3.326 μm. Atmospheric modelling leads us to conclude that a temperature inversion of approximately 300 K centred at 1–10 mbar replicates the feature. This represents an atmospheric temperature inversion for a Jupiter-like atmosphere without irradiation from a host star. A plausible explanation for the strong inversion is heating by auroral processes, although other internal and external dynamical processes cannot be ruled out. The best-fitting model rules out the contribution of H₃⁺emission, which is prominent in Solar System gas giants. However, this is consistent with rapid destruction of H₃⁺at the higher pressure where the W1935 emission originates⁴.

We present results from conducting a theoretical chemical analysis of a sample of benchmark companion brown dwarfs whose primary star is of type F, G, or K. We summarize the entire known sample of these types of companion systems, termed “compositional benchmarks,” that are present in the literature or recently published as key systems of study in order to best understand brown dwarf chemistry and condensate formation. Via mass balance and stoichiometric calculations, we predict a median brown dwarf atmospheric oxygen sink of${17.8}_{-2.3}^{+1.7}\%$by utilizing published stellar abundances in the local solar neighborhood. Additionally, we predict a silicate condensation sequence such that atmospheres with bulk Mg/Si ≲0.9 will form enstatite (MgSiO₃) and quartz (SiO₂) clouds, and atmospheres with bulk Mg/Si ≳0.9 will form enstatite and forsterite (Mg₂SiO₄) clouds. The implications of these results on C/O ratio trends in substellar-mass objects and the utility of these predictions in future modeling work are discussed.

Retrieval methods are a powerful analysis technique for modelling exoplanetary atmospheres by estimating the bulk physical and chemical properties that combine in a forward model to best fit an observed spectrum, and they are increasingly being applied to observations of directly imaged exoplanets. We have adapted taurex3, the Bayesian retrieval suite, for the analysis of near-infrared spectrophotometry from directly imaged gas giant exoplanets and brown dwarfs. We demonstrate taurex3’s applicability to sub-stellar atmospheres by presenting results for brown dwarf benchmark GJ 570D which are consistent with previous retrieval studies, whilst also exhibiting systematic biases associated with the presence of alkali lines. We also present results for the cool exoplanet 51 Eri b, the first application of a free chemistry retrieval analysis to this object, using spectroscopic observations from GPI and SPHERE. While our retrieval analysis is able to explain spectroscopic and photometric observations without employing cloud extinction, we conclude this may be a result of employing a flexible temperature-pressure profile which is able to mimic the presence of clouds. We present Bayesian evidence for an ammonia detection with a 2.7σ confidence, the first indication of ammonia in a directly imaged exoplanetary atmosphere. This is consistent with this molecule being present in brown dwarfs of a similar spectral type. We demonstrate the chemical similarities between 51 Eri b and GJ 570D in relation to their retrieved molecular abundances. Finally, we show that overall retrieval conclusions for 51 Eri b can vary when employing different spectral data and modelling components, such as temperature–pressure and cloud structures.

Brown dwarf spectra offer vital testbeds for our understanding of the chemical and physical processes that sculpt substellar atmospheres. Recently, atmospheric retrieval approaches have been successfully applied to low-resolution (R∼ 100) spectra of L, T, and Y dwarfs, yielding constraints on the chemical abundances and temperature structures of these atmospheres. Medium-resolution (R∼ 10³) spectra of brown dwarfs offer additional insight, as molecular features are more easily disentangled and the thermal structure of the upper atmosphere is better probed. We present results from a GPU-based retrieval analysis of a high signal-to-noise, medium-resolution (R∼ 6000) FIRE spectrum from 0.85 to 2.5μm of the T9 dwarf UGPS J072227.51–054031.2. At 60× higher spectral resolution than previous brown dwarf retrievals, a number of novel challenges arise. We examine the effect of different opacity sources, in particular for CH₄. Furthermore, we find that flaws in the data like errors from order stitching can bias our constraints. We compare these retrieval results to those for anR∼ 100 spectrum of the same object, revealing how constraints on atmospheric abundances and temperatures improve by an order of magnitude or more with increased spectral resolution. In particular, we can constrain the abundance of H₂S, which is undetectable at lower spectral resolution. While these medium-resolution retrievals offer the potential of precise, stellar-like constraints on atmospheric abundances (∼0.02 dex), our retrieved radius is unphysically small ($R={0.50}_{-0.01}^{+0.01}$R_Jup), indicating shortcomings with our modeling framework. This work is an initial investigation into brown dwarf retrievals at medium spectral resolution, offering guidance for future ground-based studies and JWST observations.

We present an atmospheric retrieval analysis of a pair of highly variable, ∼200 Myr old, early T type planetary-mass exoplanet analogs SIMP J01365662+0933473 and 2MASS J21392676+0220226 using the Brewster retrieval framework. Our analysis, which makes use of archival 1–15μm spectra, finds almost identical atmospheres for both objects. For both targets, we find that the data is best described by a patchy, high-altitude forsterite (Mg₂SiO₄) cloud above a deeper, optically thick iron (Fe) cloud. Our model constrains the cloud properties well, including the cloud locations and cloud particle sizes. We find that the patchy forsterite slab cloud inferred from our retrieval may be responsible for the spectral behavior of the observed variability. Our retrieved cloud structure is consistent with the atmospheric structure previously inferred from spectroscopic variability measurements, but clarifies this picture significantly. We find consistent C/O ratios for both objects, which supports their formation within the same molecular cloud in the Carina-Near moving group. Finally, we note some differences in the constrained abundances of H₂O and CO, which may be caused by data quality and/or astrophysical processes such as auroral activity and their differing rotation rates. The results presented in this work provide a promising preview of the detail with which we will characterize extrasolar atmospheres with JWST, which will yield higher-quality spectra across a wider wavelength range.

We present results from an atmospheric retrieval analysis of Gl 229B using the Brewster retrieval code. We find the best fit model to be cloud-free, consistent with the T dwarf retrieval work of Line et al.; Zalesky et al. and Gonzales et al. Fundamental parameters (mass, radius, log(L_Bol/L_Sun), log(g)) determined from our model agree within 1σto SED-derived values, except forT_effwhere our retrievedT_effis approximately 100 K cooler than the evolutionary model-based SED value. We find a retrieved mass of${50}_{-9}^{+12}$M_Jup, however, we also find that the observables of Gl 229B can be explained by a cloud-free model with a prior on mass at the dynamical value, 70M_Jup. We are able to constrain abundances for H₂O, CO, CH₄, NH₃, Na and K and find a supersolar C/O ratio as compared to its primary, Gl 229A. We report an overall subsolar metallicity due to atmospheric oxygen depletion, but find a solar [C/H], which matches that of the primary. We find that this work contributes to a growing trend in retrieval-based studies, particularly for brown dwarfs, toward supersolar C/O ratios and discuss the implications of this result on formation mechanisms and internal physical processes, as well as model biases.

Comparisons of atmospheric retrievals can reveal powerful insights on the strengths and limitations of our data and modeling tools. In this paper, we examine a sample of five L dwarfs of similar effective temperature (T_eff) or spectral type to compare their pressure–temperature (P-T) profiles. Additionally, we explore the impact of an object’s metallicity and the signal-to-noise ratio (S/N) of the observations on the parameters we can retrieve. We present the first atmospheric retrievals: 2MASS J15261405+2043414, 2MASS J05395200−0059019, 2MASS J15394189−0520428, and GD 165B increasing the small but growing number of L dwarfs retrieved. When compared to the atmospheric retrievals of SDSS J141624.08+134826.7, a low-metallicity d/sdL7 primary in a wide L+T binary, we find that similarT_effsources have similar P-T profiles with metallicity differences impacting the relative offset between their P-T profiles in the photosphere. We also find that for near-infrared spectra, when the S/N is ≳80 we are in a regime where model uncertainties dominate over data measurement uncertainties. As such, S/N does not play a role in the retrieval’s ability to distinguish between a cloud-free and cloudless model, but may impact the confidence of the retrieved parameters. Lastly, we also discuss how to break cloud model degeneracies and the impact of extraneous gases in a retrieval model.