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Manipulating Excited State Properties of Iridium Phenylpyridine Complexes with “Push–Pull” Substituents

https://doi.org/10.1021/acs.inorgchem.2c02269

Turner, Emigdio E.; Breen, Douglas J.; Kosgei, Gilbert; Crandall, Laura A.; Curtin, Gregory M.; Jakubikova, Elena; O’Donnell, Ryan M.; Ziegler, Christopher J.; Rack, Jeffrey J. (November 2022, Inorganic Chemistry)

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Understanding the Photochemical Properties of Polythiophene Polyelectrolyte Soft Aggregates with Sodium Dodecyl Sulfate for Antimicrobial Activity

https://doi.org/10.1021/acsami.1c18553

Livshits, Maksim Y.; Yang, Jianzhong; Maghsoodi, Fahimeh; Scheberl, Andrea; Greer, Samuel M.; Khalil, Mohammed I.; Strach, Edward; Brown, Dylan; Stein, Benjamin W.; Reimhult, Erik; et al (December 2021, ACS Applied Materials & Interfaces)

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Slow ³ MLCT Formation Prior to Isomerization in Ruthenium Carbene Sulfoxide Complexes

https://doi.org/10.1021/acs.inorgchem.1c01558

Thapa Magar, Rajani; Breen, Douglas J.; Schrage, Briana R.; Ziegler, Christopher J.; Rack, Jeffrey J. (November 2021, Inorganic Chemistry)

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Evidence for a lowest energy ³ MLCT excited state in [Fe(tpy)(CN) ₃ ] ⁻

https://doi.org/10.1039/d1cc01090e

Vittardi, Sebastian B.; Magar, Rajani Thapa; Schrage, Briana R.; Ziegler, Christopher J.; Jakubikova, Elena; Rack, Jeffrey J. (May 2021, Chemical Communications)
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Transient absorption data of [Fe II (tpy)(CN) 3 ] − reveals spectroscopic signatures indicative of 3 MLCT with a ∼10 ps kinetic component. These data are supported by DFT and TD-DFT calculations, which show that excited state ordering is responsive to the number of cyanide ligands on the complex.
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Finely Designed P3HT-Based Fully Conjugated Graft Polymer: Optical Measurements, Morphology, and the Faraday Effect

https://doi.org/10.1021/acsami.0c08170

Liu, Xunshan; Turner, Emigdio E.; Sharapov, Valerii; Yuan, Dafei; Awais, Mohammad A.; Rack, Jeffrey J.; Yu, Luping (July 2020, ACS Applied Materials & Interfaces)

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