skip to main content


Search for: All records

Award ID contains: 1944495

Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

  1. Free, publicly-accessible full text available August 15, 2024
  2. Free, publicly-accessible full text available May 23, 2024
  3. Abstract Adsorption-induced deformation is a change in geometrical dimensions of an adsorbent material caused by gas or liquid adsorption on its surface. This phenomenon is universal and sensitive to adsorbent properties, which makes its prediction a challenging task. However, the pure academic interest is complemented by its importance in a number of engineering applications with porous materials characterization among them. Similar to classical adsorption-based characterization methods, the deformation-based ones rely on the quality of the underlying theoretical framework. This fact stimulates the recent development of qualitative and quantitative models toward the more detailed description of a solid material, e.g. account of non-convex and corrugated pores, calculations of adsorption stress in realistic three-dimension solid structures, the extension of the existing models to new geometries, etc. The present review focuses on the theoretical description of adsorption-induced deformation in micro and mesoporous materials. We are aiming to cover recent theoretical works describing the deformation of both ordered and disordered porous bodies. 
    more » « less
  4. null (Ed.)
    Fluids confined in nanopores are ubiquitous in nature and technology. In recent years, the interest in confined fluids has grown, driven by research on unconventional hydrocarbon resources -- shale gas and shale oil, much of which are confined in nanopores. When fluids are confined in nanopores, many of their properties differ from those of the same fluid in the bulk. These properties include density, freezing point, transport coefficients, thermal expansion coefficient, and elastic properties. The elastic moduli of a fluid confined in the pores contribute to the overall elasticity of the fluid-saturated porous medium and determine the speed at which elastic waves traverse through the medium. Wave propagation in fluid-saturated porous media is pivotal for geophysics, as elastic waves are used for characterization of formations and rock samples. In this paper, we present a comprehensive review of experimental works on wave propagation in fluid-saturated nanoporous media, as well as theoretical works focused on calculation of compressibility of fluids in confinement. We discuss models that bridge the gap between experiments and theory, revealing a number of open questions that are both fundamental and applied in nature. While some results were demonstrated both experimentally and theoretically (e.g. the pressure dependence of compressibility of fluids), others were theoretically predicted, but not verified in experiments (e.g. linear scaling of modulus with the pore size). Therefore, there is a demand for the combined experimental-modeling studies on porous samples with various characteristic pore sizes. The extension of molecular simulation studies from simple model fluids to the more complex molecular fluids is another open area of practical interest. 
    more » « less
  5. null (Ed.)