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Bodkin, Lauren N ; Krajnak, Zachary A ; Dong, Ruiqi ; Osuji, Chinedum O ; Gin, Douglas L ( , Soft Matter)
Two new, cross-linkable, phosphobetaine zwitterionic amphiphiles were found to form a type II bicontinuous cubic (QII) phase with aq. NH4Cl. Upon polymerization, they form 3D-nanoporous membrane materials that are not susceptible to ion exchange.
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Stable cross-linked lyotropic gyroid mesophases from single-head/single-tail cross-linkable monomersImran, Omar Q. ; Li, Patrick ; Kim, Na Kyung ; Gin, Douglas L. ; Osuji, Chinedum O. ( , Chemical Communications)A single-head/single-tail surfactant with a polymerizable group at each end is presented as a new simplified motif for intrinsically cross-linkable, gyroid-phase lyotropic mesogens. The resulting nanoporous polymer networks exhibit excellent structural stability in various solvents and are capable of molecular size discrimination.more » « less