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Abstract Sulfate is a potential pollutant and important nutrient linked with the nitrogen, carbon, and phosphorus cycles. The importance of different anthropogenic sulfate sources in suburban streams (septic systems, fertilizer, road salt, and infrastructure) is uncertain, and the temporal dynamics of stream export sparsely documented. We study sources and export dynamics of sulfate in suburban and forested headwater catchments. Stream baseflow discharge and sulfate concentrations were strongly positively correlated in both watersheds with the highest values in spring. Suburban concentrations and fluxes (2.48–7.5 mg/L or 25.8–78.1 μM, 16.6 kg/ha/yr) were consistently higher than forested (0.56–2.78 mg/L or 5.8–28.9 μM, 5 kg/ha/yr). Following precipitation, sulfate concentrations in both forested and suburban streams increased to concentrations above pre‐storm values and remained high after peak discharge. These dynamics suggest that both catchments have a large pool of sulfate that can be mobilized under wet conditions. Ridge‐top forest soil samples contained 210 kg/ha stored, extractable sulfate. Current atmospheric sulfate deposition rates (5–7 kg/ha/yr) are approximately in balance with sulfate export in the forested stream. In the suburban watershed, we estimated septic fields contribute up to 11 kg/ha/yr (about half from surfactants) and lawn care up to 4.3 kg/ha/yr and are the most likely sources of elevated stream sulfate. Sulfate sulfur (4.9–5.8‰ forested; 6.1–7.0‰ suburban) and oxygen isotope values (0.7–2.0‰ forested; −0.1–4.1‰ suburban) are consistent with this interpretation, but do not provide strong corroboration due to large variation and overlap in estimated source values. 

Abstract Solute transit or travel time distributions (TTDs) in catchments are relevant to both hydrochemical response and inference of hydrologic mechanisms. Long‐tailed TTDs and fractal scaling behavior of stream concentration power spectra (∼1/frequency, or 1/frequency to a power <2) are widely observed in catchment studies. In several catchments, a significant fraction of streamflow is derived from groundwater in shallow fractured bedrock, where matrix diffusion significantly influences solute transport. I present frequency and time domain theoretical analyses of solute transport to quantify the influence of matrix diffusion on fractal scaling and long‐tailed TTDs. The theoretical concentration power spectra exhibit fractal scaling, and the corresponding TTDs resemble a gamma distribution. The tails of the TTDs are influenced by accessible matrix width, exhibiting a sustained power‐law (rather than exponential) decline for large matrix widths. Application to an experimental catchment shows that theoretical spectra match previously reported power spectral estimates derived from concentration measurements. 

Abstract The hydrologic dynamics and geomorphic evolution of watersheds are intimately coupled—runoff generation and water storage are controlled by topography and properties of the surface and subsurface, while also affecting the evolution of those properties over geologic time. However, the large disparity between their timescales has made it difficult to examine interdependent controls on emergent hydrogeomorphic properties, such as hillslope length, drainage density, and extent of surface saturation. In this study, we develop a new model coupling hydrology and landscape evolution to explore how runoff generation affects long‐term catchment evolution, and analyze numerical results using a nondimensional scaling framework. We focus on hydrologic processes dominating in humid climates where storm runoff primarily arises from shallow subsurface flow and from precipitation on saturated areas. The model solves hydraulic groundwater equations to predict the water‐table elevation given prescribed, constant groundwater recharge. Water in excess of the subsurface capacity for transport becomes overland flow, which generates shear stress on the surface and may detach and transport sediment. This affects the landscape form that in turn affects runoff generation. We show that (a) four dimensionless parameters describe the possible steady state landscapes that coevolve under steady recharge; (b) hillslope length increases with increasing transmissivity relative to the recharge rate; (c) three topographic metrics—steepness index, Laplacian curvature, and topographic index—together provide a basis for interpreting landscapes that have coevolved with runoff generated via shallow subsurface flow. Finally we discuss the possibilities and limitations for quantitative comparisons between the model results and real landscapes.