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Award ID contains: 2018784

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  1. Lithium transference in a multivalent electrolyte containing bulky, star-shaped anions is compared using three experimental techniques, namely, electrochemical polarization, PFG-NMR and electrophoretic NMR. 
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  2. We demonstrate that contrary to previous reports, transference number decreases with increasing degree of polymerization in non-aqueous lithium-bearing polyelectrolyte solutions that have been proposed as next-generation battery electrolytes. 
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  3. Uranium- and thorium-iridium multimetallic species with unprecedented actinide–iridium interactions are preparedviasalt-elimination reactions between U/Th halides and K[IrCp*H3]. 
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