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Current and previous thermospheric remote sensing missions use N₂Lyman‐Birge‐Hopfield (LBH) band dayglow emission measurements to retrieve line‐of‐sight thermospheric composition and temperature. The precision of thermospheric composition and temperature retrieved from observations depends on the uncertainty in the relative LBH vibrational populations. In the laboratory, electron impact induced LBH emission measurements have shown that the relative vibrational populations change with gas pressure. However, it is not fully understood how these populations change for dayglow observations where the emissions that contribute to the observations vary with solar illumination and line‐of‐sight geometry. We quantify the relative vibrational populations as a function of solar zenith angle (SZA) and tangent altitude using Global‐scale Observations of Limb and Disk mission's LBH dayglow observations. We find that, while some lower vibrational levels show potential enhancement with increasing pressure (decreasing altitude), in general, they do not change significantly with SZA or tangent altitude for dayglow observations. The vibrational populations can thus be assumed as fixed parameters when retrieving neutral disk temperatures from remotely sensed LBH dayglow observations.

 

We have measured in the laboratory the far ultraviolet (FUV: 125.0–170.0 nm) cascade-induced spectrum of the Lyman-Birge-Hopfield (LBH) band system (a 1Πg → X 1Σg+) of N2 excited by 30–200 eV electrons. The cascading transition begins with two processes: radiative and collision-induced electronic transitions (CIETs) involving two states (a′ 1Σu− and w 1Δu → a 1Πg), which are followed by a cascade induced transition a 1Πg → X 1Σg+. Direct excitation to the a-state produces a confined LBH spectral glow pattern around an electron beam. We have spatially resolved the electron induced glow pattern from an electron beam colliding with N2 at radial distances of 0–400 mm at three gas pressures. This imaging measurement is the first to isolate spectral measurements in the laboratory of single-scattering electron-impact-induced-fluorescence from two LBH emission processes: direct excitation, which is strongest in emission near the electron beam axis; and cascading-induced, which is dominant far from the electron beam axis. The vibrational populations for vibrational levels from v′=0–2 of the a 1Πg state are enhanced by CIETs, and the emission cross sections of the LBH band system for direct and cascading-induced excitation are provided at 40, 100, and 200 eV