skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Search for: All records

Award ID contains: 2037704

Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

  1. Secondary organic aerosols contribute a large fraction to atmospheric aerosols. The phase states of secondary organic aerosols influence heterogeneous and multiphase chemistry in the atmosphere and thus climate. In previous studies we have used the dual tandem differential mobility analyzer technique to characterize the temperature- and humidity-dependent viscosity and glass transition temperature of suspended particles. However, the technique requires high particle number concentrations, is a complex setup, is expensive, and measurements are time consuming. Here we demonstrate a new simplified and more cost-effective method to obtain similar data. The technique was used to measure the temperature where the viscosity is ∼107 Pa s for submicron particles composed of binary and ternary mixtures of the sucrose/tartaric acid/citric acid system. Sucrose, tartaric acid and citric acid are taken as proxies for viscous organic aerosol components in the atmosphere. A subset of data were compared to measurements with the dual-tandem differential mobility analyzer method. Results show good agreement between the two techniques. The same mixed chemical systems were modeled using an updated version of the parametric phase diagram model described in Kasparoglu et al. (2021, https://doi.org/10.5194/acp-21-1127-2021) as well as the predictions with the viscosity module of the Aerosol Inorganic–Organic Mixtures Functional groups Activity Coefficients model (AIOMFAC-VISC). Results show that appropriately parameterized mixing rules are suitable to describe these mixtures. We anticipate that the new technique will accelerate discovery of aerosol phase transitions in aerosol research. 
    more » « less