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Chemical speciation models based upon the Pitzer activity coefficient equations, including the propagation of uncertainties. II. Tris buffers in artificial seawater at 25 °C, and an assessment of the seawater ‘Total’ pH scale

https://doi.org/10.1016/j.marchem.2022.104096

Clegg, Simon L. ; Humphreys, Matthew P. ; Waters, Jason F. ; Turner, David R. ; Dickson, Andrew G. ( July 2022 , Marine Chemistry)

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Chemical speciation models based upon the Pitzer activity coefficient equations, including the propagation of uncertainties: Artificial seawater from 0 to 45 °C

https://doi.org/10.1016/j.marchem.2022.104095

Humphreys, Matthew P. ; Waters, Jason F. ; Turner, David R. ; Dickson, Andrew G. ; Clegg, Simon L. ( July 2022 , Marine Chemistry)

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Technical note: Interpreting pH changes

https://doi.org/10.5194/bg-18-1407-2021

Fassbender, Andrea J. ; Orr, James C. ; Dickson, Andrew G. ( January 2021 , Biogeosciences)

Abstract. The number and quality of ocean pH measurements have increasedsubstantially over the past few decades such that trends, variability, andspatial patterns of change are now being evaluated. However, comparing pHchanges across domains with different initial pH values can be misleadingbecause a pH change reflects a relative change in the hydrogen ionconcentration ([H+], expressed in mol kg−1) rather than anabsolute change in [H+]. We recommend that [H+] be used inaddition to pH when describing such changes and provide three examplesillustrating why.
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