skip to main content
Explore Scholarly Publications and Datasets in the NSF-PAR

  • Home
  • Search Results
  • Page 1 of 1

Search for: All records

Award ID contains: 2102298

Note: When clicking on a Digital Object Identifier (DOI) number, you will be taken to an external site maintained by the publisher. Some full text articles may not yet be available without a charge during the embargo (administrative interval).
What is a DOI Number?

Some links on this page may take you to non-federal websites. Their policies may differ from this site.

  1. ; ; ( , ChemElectroChem)
    Abstract

    Electrochemical applications of metal organic frameworks (MOFs) are of considerable current interest. Due to the large surface area exposed to solution, MOFs are potentially useful electrode materials for sensing inner‐sphere analytes, such as reactive oxygen species. Herein, we electrodeposited copper benzene tricarboxylate MOF (HKUST‐1) into the cavity of an open carbon nanopipette (CNP) to produce a CNP‐MOF nanoelectrode. Unlike electronically conductive metal or carbon electrodes, the electrochemical response of CNP–MOFs relies on oxidation/reduction of Cu(I)/Cu(II) nodes in the porous nanostructure. Nevertheless, sigmoidal steady‐state voltammograms with a well‐defined plateau current have been recorded for simple redox mediators, for example, ferrocenemethanol. A linear calibration curve obtained for the hydrogen peroxide reduction suggests that CNP–MOFs can potentially be useful as nanosensors for peroxide.

    Full Text Available 
  2. ; ; ( , Analytical Chemistry)
    Full Text Available 
  3. ; ; ; ; ; ; ; ( , The Journal of Physical Chemistry C)
    Full Text Available 
  4. ; ; ; ( , Journal of the American Chemical Society)
    Full Text Available