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We present a modular quasi-optical pulse slicer designed for use at terahertz (THz) frequencies. Given a quasi-cw input, the two outputs of a module are (1) a pulse with programmable duration and (2) its complement. The quasi-optical design incorporates a laser-driven silicon switch at Brewster's angle to the incoming THz beam, which limits undesired reflections before the switch is activated such that THz power is only transmitted when the switch is “on.” An “off” switch ensures that no power is leaked after the pulse and that the switching profile is sharp. The slicer's small footprint (0.048×0.072×0.162 m3) and small insertion loss (1.2 dB at 320 GHz) as well as high switching efficiency (∼70%) allows modules to be stacked to create multiple pulses. The output channel that is not used for experiments can be used for concurrent analysis of beam parameters. Stacking modular assemblies will enable more complex sequences of kW-level pulses than are currently achievable for applications including free-electron-laser or gyrotron-powered pulsed electron spin resonance at high magnetic fields. 

Here, we present a rapidly prototyped, cost-efficient, and 3D printed quasi-optical sample holder for improving the signal-to-noise ratio (SNR) in modern, resonator-free, and high-field electron paramagnetic resonance (HFEPR) spectrometers. Such spectrometers typically operate in induction mode: The detected EPR (“cross-polar”) signal is polarized orthogonal to the incident (“co-polar”) radiation. The sample holder makes use of an adjustable sample positioner that allows for optimizing the sample position to maximize the 240-gigahertz magnetic fieldB₁and a rooftop mirror that allows for small rotations of the microwave polarization to maximize the cross-polar signal and minimize the co-polar background. When optimally tuned, the sample holder was able to improve co-polar isolation by ≳20 decibels, which is proven beneficial for maximizing the SNR in rapid-scan, pulsed, and continuous-wave EPR experiments. In rapid-scan mode, the improved SNR enabled the recording of entire EPR spectra of a narrow-line radical in millisecond time scales, which, in turn, enabled real-time monitoring of a sample’s evolving line shape.