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Flux Growth of La ₃ MC ₂ ( M = Sb, Bi, Te), a New Family of Ternary Carbides

https://doi.org/10.1002/zaac.202500046

Marzano, Luke; Uddin, Mohammed_Sahab; Zareihassangheshlaghi, Amirhossein; Araoyinbo, Olufemi; Hernandez, Juan; Latturner, Susan (June 2025, Zeitschrift für anorganische und allgemeine Chemie)

Reactions of carbon with a heavy main group metal (M = Sb, Bi, or Te) in an excess of lanthanum/nickel eutectic flux lead to formation of a family of carbide compounds La₃MC₂with a new structure type. The monoclinic structure features C₂⁴⁻anions octahedrally coordinated by six La³⁺cations, andManions surrounded by 8 La³⁺cations. These compounds are not charge‐balanced and lie on the border between intermetallic carbides and mixed anion salts. Density of states calculations show a pseudogap at the Fermi level for La₃BiC₂, which indicates that this compound is a poor metal with optimized LaBi bonding interactions.
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Lanthanide Borocarbides Ln ₃ BC ₂ X _n (Ln = La–Pr; X = H, F, Cl) Grown from Metal Flux: From Magnetic Ordering to Superconductivity

https://doi.org/10.1021/acs.chemmater.4c02111

Larson, James T; Wix, Katelyn; Oladehin, Olatunde; Baumbach, Ryan; Wang, Xiaoping; Latturner, Susan E (October 2024, Chemistry of Materials)

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Temperature-Dependent Products in Gallium Flux Reactions of Cerium and Transition Metals

https://doi.org/10.1021/acs.inorgchem.4c00797

Uddin, Md Sahab; Zareihassangheshlaghi, Amirhossein; Latturner, Susan E (July 2024, Inorganic Chemistry)

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Synthesis of Zintl Phase Metal Silicide Thermoelectric Materials in Magnesium/Zinc Flux

https://doi.org/10.1021/acs.inorgchem.4c01079

Zareihassangheshlaghi, Amirhossein; Galeano-Cabral, Jorge; Uddin, Md Sahab; Schundelmier, Benny; Wei, Kaya; Baumbach, Ryan E; Latturner, Susan E (July 2024, Inorganic Chemistry)

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Bismuth Flux Growth of Mn ₈ Zn _1.8 Bi _7.4 , a Ferromagnetic Relative of MnBi

https://doi.org/10.1021/acs.cgd.3c01416

Marzano, Luke; Uddin, Md Sahab; Larson, James T; Latturner, Susan E (March 2024, Crystal Growth & Design)

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Metal Flux Growth of Lanthanide Carbide Hydrides Using Anthracene

https://doi.org/10.1021/acs.inorgchem.3c01511

Larson, James T.; Wix, Katelyn D.; Chen, Banghao; Latturner, Susan E. (August 2023, Inorganic Chemistry)

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Ce ₄ B ₂ C ₂ F _0.14 H _2.26 : Cerium Borocarbides with Fluoride and Hydride Interstitials Grown from Ce/Cu Flux

https://doi.org/10.1021/acs.cgd.3c00512

Larson, James T.; Hoffmann, Christina; Latturner, Susan E. (August 2023, Crystal Growth & Design)

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Flux Growth of an Intermetallic with Interstitial Fluorides via Decomposition of a Fluorocarbon

https://doi.org/10.1021/acs.inorgchem.2c03642

Larson, James T.; Latturner, Susan E. (January 2023, Inorganic Chemistry)

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Flux Growth of Cerium Nickel Gallides Studied by In Situ Neutron Diffraction

https://doi.org/10.1021/acs.inorgchem.2c02588

Haddock, Jo W.; Barton, Zach J.; Feng, Keke; Baumbach, Ryan E.; Zhang, Qiang; Latturner, Susan E. (October 2022, Inorganic Chemistry)

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