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  1. Abstract Quantum systems have entered a competitive regime in which classical computers must make approximations to represent highly entangled quantum states1,2. However, in this beyond-classically-exact regime, fidelity comparisons between quantum and classical systems have so far been limited to digital quantum devices2–5, and it remains unsolved how to estimate the actual entanglement content of experiments6. Here, we perform fidelity benchmarking and mixed-state entanglement estimation with a 60-atom analogue Rydberg quantum simulator, reaching a high-entanglement entropy regime in which exact classical simulation becomes impractical. Our benchmarking protocol involves extrapolation from comparisons against an approximate classical algorithm, introduced here, with varying entanglement limits. We then develop and demonstrate an estimator of the experimental mixed-state entanglement6, finding our experiment is competitive with state-of-the-art digital quantum devices performing random circuit evolution2–5. Finally, we compare the experimental fidelity against that achieved by various approximate classical algorithms, and find that only the algorithm we introduce is able to keep pace with the experiment on the classical hardware we use. Our results enable a new model for evaluating the ability of both analogue and digital quantum devices to generate entanglement in the beyond-classically-exact regime, and highlight the evolving divide between quantum and classical systems. 
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  2. Despite its long history, a canonical formulation of quantum ergodicity that applies to general classes of quantum dynamics, including driven systems, has not been fully established. Here we introduce and study a notion of quantum ergodicity for closed systems with time-dependent Hamiltonians, defined as statistical randomness exhibited in their longtime dynamics. Concretely, we consider the temporal ensemble of quantum states (time-evolution operators) generated by the evolution, and investigate the conditions necessary for them to be statistically indistinguishable from uniformly random states (operators) in the Hilbert space (space of unitaries). We find that the number of driving frequencies underlying the Hamiltonian needs to be sufficiently large for this to occur. Conversely, we show that statistical —indistinguishability up to some large but finite moment—can already be achieved by a quantum system driven with a single frequency, i.e., a Floquet system, as long as the driving period is sufficiently long. Our work relates the complexity of a time-dependent Hamiltonian and that of the resulting quantum dynamics, and offers a fresh perspective to the established topics of quantum ergodicity and chaos from the lens of quantum information. Published by the American Physical Society2024 
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    Free, publicly-accessible full text available December 1, 2025
  3. We report universal statistical properties displayed by ensembles of pure states that naturally emerge in quantum many-body systems. Specifically, two classes of state ensembles are considered: those formed by (i) the temporal trajectory of a quantum state under unitary evolution or (ii) the quantum states of small subsystems obtained by partial, local projective measurements performed on their complements. These cases, respectively, exemplify the phenomena of “Hilbert-space ergodicity” and “deep thermalization.” In both cases, the resultant ensembles are defined by a simple principle: The distributions of pure states have maximum entropy, subject to constraints such as energy conservation, and effective constraints imposed by thermalization. We present and numerically verify quantifiable signatures of this principle by deriving explicit formulas for all statistical moments of the ensembles, proving the necessary and sufficient conditions for such universality under widely accepted assumptions, and describing their measurable consequences in experiments. We further discuss information-theoretic implications of the universality: Our ensembles have maximal information content while being maximally difficult to interrogate, establishing that generic quantum state ensembles that occur in nature hide (scramble) information as strongly as possible. Our results generalize the notions of Hilbert-space ergodicity to time-independent Hamiltonian dynamics and deep thermalization from infinite to finite effective temperature. Our work presents new perspectives to characterize and understand universal behaviors of quantum dynamics using statistical and information-theoretic tools. Published by the American Physical Society2024 
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    Free, publicly-accessible full text available November 1, 2025