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We study the universal behavior of a class of active colloids whose design is inspired by the collective dynamics of natural systems such as schools of fish and flocks of birds. These colloids, with off-center repulsive interaction sites, self-organize into polar swarms exhibiting long-range order and directional motion without significant hydrodynamic interactions. Our simulations show that the system transitions from motile perfect crystals to solid-like, liquid-like, and gas-like states depending on noise levels, repulsive interaction strength, and particle density. By analyzing swarm polarity and hexatic bond order parameters, we demonstrate that effective volume fractions based on force-range and torque-range interactions explain the system's universal behavior. This work lays a groundwork for biomimetic applications utilizing the cooperative polar dynamics of active colloids.more » « lessFree, publicly-accessible full text available March 3, 2026
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By introducing geometry-based phoresis kernels, we establish a direct connection between the translational and rotational velocities of a phoretic sphere and the distributions of the driving fields or fluxes. The kernels quantify the local contribution of the field or flux to the particle dynamics. The field kernels for both passive and active particles share the same functional form, depending on the position-dependent surface phoretic mobility. For uniform phoretic mobility, the translational field kernel is proportional to the surface normal vector, while the rotational field kernel is zero; thus, a phoretic sphere with uniform phoretic mobility does not rotate. As case studies, we discuss examples of a self-phoretic axisymmetric particle influenced by a globally-driven field gradient, a general scenario for axisymmetric self-phoretic particle and two of its special cases, and a non-axisymmetric active particle.more » « less
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We revisit Brenner's seminal work on the Stokes resistance of a slightly deformed sphere (Chem. Engng Sci., vol. 19, 1964, p. 519), evaluate its range of validity and extend its applicability to higher deformations for axisymmetric particles, using hydrodynamic radius as the measure of Stokes resistance. Brenner's method solves the flow around a slightly deformed sphere through two mapping steps: the first mapping translates the surface velocity on the deformed sphere to that over a reference sphere of arbitrary radius using an asymptotic expansion of the flow field in terms of deformation amplitude and a Taylor expansion of the velocity field around the surface of the reference sphere. Subsequently, the second mapping extrapolates the velocity field from the surface of the reference sphere to any point in the fluid using Lamb's general solution for Stokes flow. While the original work addresses slightly deformed spheres to a linear order in deformation amplitude, we demonstrate that the first mapping, in combination with axisymmetric spectral modes (J. Fluid Mech., vol. 936, 2022, R1), can accommodate significant deformations to arbitrary orders of perturbation, and thus is not limited to slightly deformed spheres. Also, while first-order analysis is suitable for nearly spherical particles, second-order terms can provide a reasonable range for significantly higher deformations.more » « less
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