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The stripping reaction of lithium will greatly impact the cyclability and safety of Li metal batteries. However, lithium pits' nucleation and growth, the origin of uneven stripping, are still poorly understood. In this study, we analyze the nucleation mechanism of Li pits and their morphology evolution with a large population and electrode area (>0.45 cm²). We elucidate the dependence of pit size and density on current density and overpotential, which is aligned with classical nucleation theory. With laser scanning confocal microscope, we reveal the preferential stripping on certain crystal grains and a new stripping mode between pure pitting and stripping without pitting. Descriptors like circularity and the aspect ratio (R) of pit radius to depth are used to quantify the evolution of lithium pits in three dimensions. As pits grow, growth predominates along the through-plane direction, surpassing the expanding rate at the in-plane direction. After analyzing more than 1000 pits at each condition, we validate that the overpotential is inversely related to the pit radius and exponentially related to the rate of nucleation. With this established nucleation-overpotential relationship, we can better understand and predict the evolution of surface area and roughness of lithium electrodes under different stripping conditions. The knowledge and methodology developed in this work will significantly benefit lithium metal batteries' charging/discharging profile design and the assessment of large-scale lithium metal foils. DOI of publication: 10.1021/acsami.4c01530 Acknowledgments: H.Z., M.U., and F.S. thank the support from the Assistant Secretary for Energy Efficiency and Renewable Energy, Office of Vehicle Technologies of the US Department of Energy through the Advanced Battery Materials Research Program. F.S. thanks the support from the National Science Foundation under Grant No. 2239690.