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Modular silver catalysts to elucidate the role of non-covalent interactions in asymmetric C‒H amidation reactions

https://doi.org/10.1016/j.checat.2025.101388

Schroeder, Emily Z; Kim, Jed H; Fu, Yue; Liu, Wentan; Liu, Peng; Schomaker, Jennifer M (May 2025, Chem Catalysis)

Free, publicly-accessible full text available May 1, 2026
Mechanistic and Computational Insights into Asymmetric Intramolecular Iron-Catalyzed Nitrene Transfer into Benzylic C–H Bonds

https://doi.org/10.1021/acscatal.5c00222

Seo, Kyeongdeok; Zhang, Yu; Trinh, Tuan Anh; Kim, Jed; Qi, Lihan; Guzei, Ilia A; Clark, Joseph R; Liu, Peng; Schomaker, Jennifer M (February 2025, ACS Catalysis)

Free, publicly-accessible full text available February 18, 2026
Reactivity of Anomalous Aziridines for Versatile Access to High Fsp ³ Amine Chemical Space

https://doi.org/10.1021/acs.accounts.4c00670

Marris, Elijah T; Rampon, Daniel S; Schomaker, Jennifer M (January 2025, Accounts of Chemical Research)

Free, publicly-accessible full text available January 21, 2026
Iron-Catalyzed Three-Component 1,2-Azidoalkylation of Conjugated Dienes via Activation of Aliphatic C‒H Bonds

https://doi.org/10.1039/D5SC00307E

Dai, Zhen-Yao Zhen-Yao; Lin, Chenxi; Hu, Derek B; Schomaker, Jennifer (January 2025, Chemical Science)

Azidoalkyation is an efficient strategy for the conversion of unsaturated precursors into nitrogen-containing structural motifs. Herein, we describe a convenient and highly regioselective iron-catalyzed 1,2-azidoalkylation of 1,3-dienes that employs TMSN3...
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Free, publicly-accessible full text available January 1, 2026
Site- and stereoselective silver-catalyzed intramolecular amination of electron-deficient heterobenzylic C–H bonds

https://doi.org/10.1039/D4SC08757G

Trinh, Tuan Anh; Cherempei, Stanislav; Rampon, Daniel S; Schomaker, Jennifer M (January 2025, Chemical Science)

Rational ligand design in a silver catalyst enables highly selective amination of electron-deficient heterobenzylic C–H bondsvianitrene transfer, with scaffold rigidity crucial for unlocking this elusive reactivity in heteroaromatic compounds.
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Free, publicly-accessible full text available January 1, 2026
Chemoselective Silver-Catalyzed Nitrene Transfer: Tunable Syntheses of Azepines and Cyclic Carbamimidates

https://doi.org/10.1021/jacs.4c08249

Schroeder, Emily Z; Lin, Chenxi; Hu, Yun; Dai, Zhen-Yao; Griffin, Amory F; Hotvedt, Thomas S; Guzei, Ilia A; Schomaker, Jennifer M (August 2024, Journal of the American Chemical Society)

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Iron-Catalyzed Site- and Regioselective 1,2-Azidoamidations of 1,3-Dienes

https://doi.org/10.1021/acs.orglett.3c03947

Dai, Zhen-Yao; Guzei, Ilia A.; Schomaker, Jennifer M. (January 2024, Organic Letters)

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Chemo- and enantioselective intramolecular silver-catalyzed aziridinations of carbamimidates

https://doi.org/10.1039/D3CC05670H

Trinh, Tuan Anh; Fu, Yue; Hu, Derek B.; Zappia, Soren A.; Guzei, Ilia A.; Liu, Peng; Schomaker, Jennifer M. (December 2023, Chemical Communications)

Transition metal-catalyzed asymmetric nitrene transfer is a powerful method to generate enantioenriched amines found in natural products and bioactive molecules.
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