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Award ID contains: 2316451

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  1. Abstract We investigated the early stages of olivine crystal growth via in situ seeded experiments in a single plagioclase-hosted melt inclusion, using a heating stage microscope. Each experiment was subjected to a cooling ramp of 7800°C/h followed by an isothermal dwell at 19°C, 38°C, 57°C, 77°C, 96°C or 129°C of undercooling. The seeds (6–16 μm in diameter Ø) grew into large crystals (Ø 80–169 μm) in 3 to 30 min through the symmetrical development of tabular, skeletal, and dendritic overgrowths as the undercooling of the system increased. Time-resolved image processing and incremental measurements of the overgrowth thicknesses indicate up to three stages of crystal growth: an acceleration stage, a linear (constant growth rate) stage, and a deceleration stage. At the isotherm, the growth velocities reach a stable maximum that in all experiments corresponds to the period of linear growth. The highest linear values are measured at the {101} interfaces, from 2.1 × 10−8 m/s at 19°C of undercooling to 4.8 × 10−7 m/s at 129°C of undercooling. Crystal growth is slower at other interfaces, in the ranges 1.9–7.6 × 10−8 m/s and 4.5 × 10−9 – 7.6 × 10−8 m/s for the {100} and {001} forms, respectively. Growth in the <010> dimension appears limited to less than 2.4 × 10−8 m/s at 129°C of undercooling. We constrain the uncertainty on these growth velocities, which includes the environmental conditions (± 8.6°C on the nominal undercooling) and the measurements of crystal lengths (underestimated by <16% at most fast interfaces). A systematic and comprehensive review of 19 pre-existing datasets indicates that our linear growth velocities are faster than most growth rates determined at comparable undercoolings. Growth rates determined as half crystal lengths divided by total time are intrinsically low estimates of the true maximum, linear growth velocities, because the total time includes periods of slower or non-growth, and measured crystal dimensions are subject to projection foreshortening or truncation. These errors can lead to values that are several times to several orders of magnitude lower than the true maximum growth rates. This study completes and refines previously published data on the crystallization kinetics of olivine, highlighting the sensitivity of growth rates to specific environmental conditions and measurement methods. We emphasize the importance of symmetrical growth and true maximum growth velocities for interpreting olivine growth histories. 
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  2. When magmas erupt at the surface, they may have undergone many changes since their inception. While olivine drives some of these changes through crystallization and fractionation, it also records the magma evolution via mineral chemistry and by trapping mineral and melt inclusions. Olivine is an effective recorder of intensive parameters, such as temperature and melt composition, and provides an outstanding petrological tool for constraining dynamic processes, such as ascent, mixing, and cooling. Olivine sheds light on magmatic puzzles that involve both mafic and more evolved magmas, with protracted and complex magmatic histories that often obscure earlier and deeper processes. This contribution summarizes the current state of how olivine helps reconstruct source-to-surface magma assembly through its chemistry, inclusions, and textures. 
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  3. Olivine occurs across the galaxy, from Earth to extraterrestrial bodies including the Moon, Mars, and asteroids, to particles of comet dust and distant debris disks. The mineral is critical to our understanding of early Solar System chronology, planetary formation processes (e.g., magma ocean solidification), crustal evolution (e.g., volcanic eruptions), and surface weathering. Olivine’s ability to shed light on these processes lies in the linkage of small, physical samples and satellite-derived data. Laboratory spectra become the basis for olivine detection and compositional interpretation in remotely sensed spectra ranging from high-resolution planetary maps to single extra-solar datapoints. In turn, petrologic studies of olivine underpin the geologic interpretations of these spectral datasets. Finally, olivine chemistry records Solar System formation conditions and relative chronology. Olivine is our bridge across time and space. 
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  4. In some ways, olivine has driven the evolution of the Solar System and likely beyond. As one of the earliest-crystallizing silicate minerals, olivine controls the initial chemical evolution of planet-wide magma oceans and individual lava flows alike. In solid aggregate form, it controls and records deformation of the mantle and smaller-scale intrusive complexes. The components of its crystal structure are mobile at high temperatures and their migration can be used to explore the timing of magmatic events. During chemical weathering, these olivine crystals capture carbon dioxide from the atmosphere as secondary minerals are formed. All of these processes take place not only on Earth, but also on other planetary bodies, making olivine ideally suited to shed light on both primordial planet-building processes and current-day volcanism and surface processes. 
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