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Grigoras, Cristina-Gabriela; Simion, Andrei Ionut (Ed.)Efficient water decolorization techniques are vital for ensuring fresh water for future generations. Azo dyes are used heavily in the textile industry and are a challenge to remove from industrial wastewater. This research expands on recent innovative work where anionic azo dyes themselves were used to functionalize track-etched porous polycarbonate filtration membranes with decolorized water obtained as a byproduct. The objective of this research is to determine whether the observed dye rejection is dependent on the magnitude of the intrinsic charge of the dye molecule or on its structure, using two selectively chosen anionic azo dye series during functionalization. The first group is a negative two intrinsic charge series with six dyes, each differing in structure, and the second group is a five-dye series that increases from −1 to −6 in intrinsic charge. Rejection measurements as a function of both time and concentration during functionalization are made using ultraviolet-visible light spectroscopy. For 100 µM aqueous dyes, comparing pre- and post-functionalization, a systematically increasing trend in the ability to functionalize porous polycarbonate based on the number of double 6-carbon ring structures in the dyes is illustrated and found to be independent of intrinsic charge.more » « less
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Babiuc-Hamilton, Maria C; Messman, William A (, Classical and Quantum Gravity)Gravitational Wave (GW) signals from binary neutron star (BNS) mergers provide critical insights into the properties of matter under extreme conditions. Due to the scarcity of observational data, numerical relativity (NR) simulations are indispensable for exploring these phenomena, without replacing the need for observational confirmation. However, simulating BNS mergers is a formidable challenge, and ensuring the consistency, reliability or convergence, especially in the post-merger, remains a work in progress. In this paper we assess the performance of current BNS merger simulations by analyzing open-source GW waveforms from five leading NR codes –SACRA,BAM,THC,Whisky, andSpEC. We focus on the accuracy of these simulations and on the effect of the equation of state on waveform predictions. We first check if different codes give similar results for similar initial data, then apply two methods to calculate convergence and quantify discretization errors. Lastly, we perform a thorough investigation into the effect of tidal interactions on key frequencies in the GW spectrum. We introduce a novel quasi-universal relation for the transient post-merger time, enhancing our understanding of remnant dynamics in this region. This detailed analysis clarifies agreements and discrepancies between these leading NR codes, and highlights necessary improvements for the advanced accuracy requirements of future GW detectors.more » « less
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