Transformations in Transition-Metal Carbonyls Containing Arsenic: Exploring the Chemistry of [Et 4 N] 2 [HAs{Fe(CO) 4 } 3 ] in the Search for Single-Source Precursors for Advanced Metal Pnictide Materials
- Award ID(s):
- 1411495
- Publication Date:
- NSF-PAR ID:
- 10016439
- Journal Name:
- Organometallics
- Volume:
- 35
- Issue:
- 4
- Page Range or eLocation-ID:
- 471 to 483
- ISSN:
- 0276-7333
- Sponsoring Org:
- National Science Foundation
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We present the synthesis, structure, and electrochemistry of K 3 [Mo 2 (SNO5) 4 Cl] 3 [Mo 2 (SNO5) 4 ] ( 1 , HSNO5 = monothiosuccinimide), the first example of a heterometallic extended metal atom node (HEMAN). The HEMAN consists of two perpendicular, intersecting lines of metal atoms formed by three [Mo 2 (SNO5) 4 Cl] − units and one [Mo 2 (SNO5) 4 ] unit tethered together by K + ions.