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Title: Transformations in Transition-Metal Carbonyls Containing Arsenic: Exploring the Chemistry of [Et 4 N] 2 [HAs{Fe(CO) 4 } 3 ] in the Search for Single-Source Precursors for Advanced Metal Pnictide Materials
Authors:
; ;
Award ID(s):
1411495
Publication Date:
NSF-PAR ID:
10016439
Journal Name:
Organometallics
Volume:
35
Issue:
4
Page Range or eLocation-ID:
471 to 483
ISSN:
0276-7333
Sponsoring Org:
National Science Foundation
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  1. We present the synthesis, structure, and electrochemistry of K 3 [Mo 2 (SNO5) 4 Cl] 3 [Mo 2 (SNO5) 4 ] ( 1 , HSNO5 = monothiosuccinimide), the first example of a heterometallic extended metal atom node (HEMAN). The HEMAN consists of two perpendicular, intersecting lines of metal atoms formed by three [Mo 2 (SNO5) 4 Cl] − units and one [Mo 2 (SNO5) 4 ] unit tethered together by K + ions.