skip to main content
US FlagAn official website of the United States government
dot gov icon
Official websites use .gov
A .gov website belongs to an official government organization in the United States.
https lock icon
Secure .gov websites use HTTPS
A lock ( lock ) or https:// means you've safely connected to the .gov website. Share sensitive information only on official, secure websites.


Title: Solar System Abundances of the Elements
Updated solar photospheric abundances are compared with meteoritic abundances. The uncertainties of solar abundances of many trace elements are considerably reduced compared to the 2003 compilation. Some of the solar rare earth elements have now assigned errors of ± 5%, approaching the accuracy of meteorite analyses. The agreement between solar abundances and CI chondrites is further improved. Problematic elements with comparatively large differences between solar and meteoritic abundances are manganese, hafnium, rubidium, gallium, and tungsten. The CI chondrites match solar abundances in refractory lithophile, siderophile, and volatile elements. All other chondrite groups differ from CI chondrites. With analytical uncertainties, there are no obvious fractionations between CI meteorites and solar abundances. Further progress will primarily come from improved solar abundance determinations. The limiting factor in the accuracy of meteorite abundances is the inherent heterogeneity of CI chondrites, primarily the Orgueil meteorite. The interstellar medium (ISM) from which the solar system formed has the same composition as the Sun for volatile and moderately volatile elements within a factor of 2. The more refractory elements of the ISM are depleted from the gas and are concentrated in grains.  more » « less
Award ID(s):
1517541
PAR ID:
10036398
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Planets, Asteriods, Comets and The Solar System, Volume 2 of Treatise on Geochemistry (Second Edition). Edited by Andrew M. Davis. Elsevier, 2014., p.15-36
Volume:
2
Page Range / eLocation ID:
15-36
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. Abstract Solar photospheric abundances and CI-chondrite compositions are reviewed and updated to obtain representative solar system abundances of the elements and their isotopes. The new photospheric abundances obtained here lead to higher solar metallicity. Full 3D NLTE photospheric analyses are only available for 11 elements. A quality index for analyses is introduced. For several elements, uncertainties remain large. Protosolar mass fractions are H (X = 0.7060), He (Y = 0.2753), and for metals Li to U (Z = 0.0187). The protosolar (C+N)/H agrees within 13% with the ratio for the solar core from the Borexino experiment. Elemental abundances in CI-chondrites were screened by analytical methods, sample sizes, and evaluated using concentration frequency distributions. Aqueously mobile elements (e.g., alkalis, alkaline earths, etc.) often deviate from normal distributions indicating mobilization and/or sequestration into carbonates, phosphates, and sulfates. Revised CI-chondrite abundances of non-volatile elements are similar to earlier estimates. The moderately volatile elements F and Sb are higher than before, as are C, Br and I, whereas the CI-abundances of Hg and N are now significantly lower. The solar system nuclide distribution curves of s-process elements agree within 4% with s-process predictions of Galactic chemical evolution models. P-process nuclide distributions are assessed. No obvious correlation of CI-chondritic to solar elemental abundance ratios with condensation temperatures is observed, nor is there one for ratios of CI-chondrites/solar wind abundances. 
    more » « less
  2. Abstract Solar wind Fe and Mg fluences (atoms/cm2) were measured from Genesis collectors. Fe and Mg have similar first ionization potentials and solar wind Fe/Mg should equal the solar ratio. Solar wind Fe/Mg is a more valid measure of solar composition than CI chondrites and can be measured more accurately than spectroscopic photospheric abundances. Mg and Fe fluences analyzed in four laboratories give satisfactory agreement. Si and diamond‐like carbon collector fluences agree for both elements. The Mg and Fe fluences are 1.731 ± 0.073 × 1012and 1.366 ± 0.058 × 1012atoms/cm2. All plausible sources of errors down to the 1% level are documented. Our value for the solar system Fe/Mg, 0.789 ± 0.048 agrees within 1 sigma errors with CI chondrites, spectroscopic photospheric abundances, and with the solar wind data from the ACE spacecraft. CI samples from asteroid Ryugu give Fe/Mg in agreement with Genesis and meteoritic CI samples despite very small sample sizes. The higher accuracy of the Genesis solar Fe/Mg permits a comparison with chondritic Fe/Mg at the 10% level. Intermeteorite Fe/Mg averages differ among the main C chondrite groups but are within, or very close to, the ±1 sigma Genesis solar Fe/Mg. 
    more » « less
  3. We review a large body of available meteoritic and stellar halogen data in the literature used for solar system abundances (i.e., representative abundances of the solar system at the time of its formation) and associated analytical problems. Claims of lower solar system chlorine, bromine and iodine abundances from recent analyses of CI-chondrites are untenable because of incompatibility of such low values with nuclear abundance systematics and independent measurements of halogens in the Sun and other stars. We suspect analytical problems associated with these peculiar rock types have led to lower analytical results in several studies. We review available analytical procedures and concentrations of halogens in chondrites. Our recommended values are close to pre-viously accepted values. Average concentrations by mass for CI-chondrites are F = 92 ± 20 ppm, Cl = 717 ± 110 ppm, Br = 3.77 ± 0.90 ppm, and I = 0.77 ± 0.31 ppm. The meteoritic abundances on the atomic scale normalized to N(Si) =106 are N(F) = 1270 ± 270, N(Cl) = 5290 ± 810, N(Br) = 12.3 ± 2.9, and N(I) = 1.59 ± 0.64. The meteoritic logarithmic abundances scaled to present-day photospheric abundances with log N(H) = 12 are A(F) = 4.61 ± 0.09, A(Cl) = 5.23 ± 0.06, A(Br) = 2.60 ± 0.09, and A(I) = 1.71 ± 0.15. These are our recommended present-day solar system abundances. These are compared to the present-day solar values derived from sunspots of N(F) = 776 ± 260, A(F) = 4.40 ± 0.25, and N(Cl) = 5500 ± 810, A(Cl) = 5.25 ± 0.12. The recommended solar system abundances based on meteorites are consistent with F and Cl abundance ratios measured independently in other stars and other astronomical environments. The recently determined chlorine abundance of 776 ± 21 ppm by Yokoyama et al. (2022) for the CI-chondrite-like asteroid Ryugu is consistent with the chlorine abundance evaluated for CI-chondrites here. Historically, the halogen abundances have been quite uncertain and unfortunately remain so. We still need reliable measurements from large, representative, and well-homogenized CI-chondrite samples. The analysis of F, Br, and I in Ryugu samples should also help to obtain more reliable halogen abundances. Updated equilibrium 50 % condensation temperatures from our previous work (Lodders, 2003; Fegley and Schaefer, 2010; Fegley and Lodders, 2018) are 713 K (F), 427 K (Cl), 392 K (Br) and 312 K (I) at a total pressure of 10^ 4 bar for a solar composition gas. We give condensation temperatures considering solid-solution as well as kinetic inhibition effects. Condensation temperatures computed with lower halogen abundances do not represent the correct condensation temperatures from a solar composition gas. 
    more » « less
  4. Comparing compositional models of the terrestrial planets provides insights into physicochemical processes that produced planet-scale similarities and differences. The widely accepted compositional model for Mars assumes Mn and more refractory elements are in CI chondrite proportions in the planet, including Fe, Mg, and Si, which along with O make up >90% of the mass of Mars. However, recent improvements in our understandings on the composition of the solar photosphere and meteorites challenge the use of CI chondrite as an analog of Mars. Here we present an alternative model composition for Mars that avoids such an assumption and is based on data from Martian meteorites and spacecraft observations. Our modeling method was previously applied to predict the Earth’s composition. The model establishes the absolute abundances of refractory lithophile elements in the bulk silicate Mars (BSM) at 2.26 times higher than that in CI carbonaceous chondrites. Relative to this chondritic composition, Mars has a systematic depletion in moderately volatile lithophile elements as a function of their condensation temperatures. Given this finding, we constrain the abundances of siderophile and chalcophile elements in the bulkMars and its core. The Martian volatility trend is consistent with <7 wt% S in its core, which is significantly lower than that assumed in most core models (i.e., >10 wt% S). Furthermore, the occurrence of ringwoodite at the Martian core-mantle boundary might have contributed to the partitioning of O and H into the Martian core. 
    more » « less
  5. null (Ed.)
    ABSTRACT The maximum temperature and radial temperature profile in a protoplanetary disc are important for the condensation of different elements in the disc. We simulate the evolution of a set of protoplanetary discs from the collapse of their progenitor molecular cloud cores as well as the dust decoupling within the discs as they evolve. We show how the initial properties of the cloud cores affect the thermal history of the protoplanetary discs using a simple viscous disc model. Our results show that the maximum mid-plane temperature in the disc occurs within 0.5 au. It increases with the initial cloud temperature and decreases with its angular velocity and the viscosity of the disc. From the observed properties of the molecular cloud cores, we find the median value of the maximum temperature is around 1250 K, with roughly 90 per cent of them being less than 1500 K – a value that is lower than the 50 per cent condensation temperatures of most refractory elements. Therefore, only cloud cores with high initial temperatures or low-angular velocities and/or low viscosities within the planet-forming discs will result in refractory-rich planetesimals. To reproduce the volatile depletion pattern of CM, CO, and CV chondrites and the terrestrial planets in Solar system, one must either have rare properties of the initial molecular cloud cores like high core temperature, or other sources of energy to heat the disc to sufficiently high temperatures. Alternatively, the volatile depletion observed in these chondrites may be inherited from the progenitor molecular cloud. 
    more » « less