Aluminyl anions are low‐valent, anionic, and carbenoid aluminum species commonly found stabilized with potassium cations from the reaction of Al‐halogen precursors and alkali compounds. These systems are very reactive toward the activation of
For decades, explorations with ground state, thermal reactions combined with pseudophase kinetic models and methods for interpreting the results have provided insights into the properties of the different regions of homogeneous association colloids. More recent successful determination of antioxidant (AO) distributions by this approach is providing new insights into AO efficiency in opaque, well‐mixed two‐phase intact emulsions and eliminating the need to separate the phases. The chemical probe reacts with AOs exclusively in the interfacial region of the emulsion, permitting simplification of the kinetic treatment, and determining its distribution between the oil, interfacial, and aqueous regions. AO distributions are obtained from the two partition constants,
Interpreting chemical reactivity in emulsions requires that reactive components
- NSF-PAR ID:
- 10041545
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- European Journal of Lipid Science and Technology
- Volume:
- 119
- Issue:
- 12
- ISSN:
- 1438-7697
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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