Two wide‐band‐capturing donor‐acceptor conjugates featuring bis‐styrylBODIPY and perylenediimide (PDI) have been newly synthesized, and the occurrence of ultrafast excitation transfer from the1PDI* to BODIPY, and a subsequent electron transfer from the1BODIPY* to PDI have been demonstrated. Optical absorption studies revealed panchromatic light capture but offered no evidence of ground‐state interactions between the donor and acceptor entities. Steady‐state fluorescence and excitation spectral recordings provided evidence of singlet‐singlet energy transfer in these dyads, and quenched fluorescence of bis‐styrylBODIPY emission in the dyads suggested additional photo‐events. The facile oxidation of bis‐styrylBODIPY and facile reduction of PDI, establishing their relative roles of electron donor and acceptor, were borne out by electrochemical studies. The electrostatic potential surfaces of the S1and S2states, derived from time‐dependent DFT calculations, supported excited charge transfer in these dyads. Spectro‐electrochemical studies on one‐electron‐oxidized and one‐electron‐reduced dyads and the monomeric precursor compounds were also performed in a thin‐layer optical cell under corresponding applied potentials. From this study, both bis‐styrylBODIPY⋅
A novel class of β‐functionalized push–pull zinc
- NSF-PAR ID:
- 10042622
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Chemistry – An Asian Journal
- Volume:
- 12
- Issue:
- 20
- ISSN:
- 1861-4728
- Page Range / eLocation ID:
- p. 2749-2762
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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