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Title: Phosphorescent 2-, 3- and 4-coordinate cyclic (alkyl)(amino)carbene (CAAC) Cu( i ) complexes
The photophysical properties of several Cu( i ) complexes coordinated with cyclic (alkyl)(amino)carbene (CAAC) ligands were examined. All the compounds were found to be phosphorescent, regardless of whether they are 2-, 3- or 4-coordinated. Aggregate and excimer emission were observed from 2-coordinate CAAC–CuCl derivatives in methylcyclohexane solution. Emission from the complex 4-coordinated with a trispyrazolylborate ligand is red-shifted with respect to both the chloro-derivative and an analogous complex with an NHC ligand.  more » « less
Award ID(s):
1661518
PAR ID:
10056652
Author(s) / Creator(s):
; ; ; ; ;
Date Published:
Journal Name:
Chemical Communications
Volume:
53
Issue:
64
ISSN:
1359-7345
Page Range / eLocation ID:
9008 to 9011
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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