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Title: Chiral Isocamphoric Acid: Founding a Large Family of Homochiral Porous Materials
Abstract

Homochiral metal–organic frameworks (MOFs) are an important class of chiral solids with potential applications in chiral recognition; however, relatively few are available. Of great importance is the availability of low‐cost, racemization‐resistant, and versatile enantiopure building blocks. Among chiral building blocks,d‐camphoric acid is highly prolific, yet, itstrans‐isomer,l‐isocamphoric acid, has remained unknown in the entire field of solid‐state materials. Its rich yet totally untapped synthetic and structural chemistry has now been investigated through the synthesis of a large family of homochiral metal isocamphorates. The first observation of diastereoisomerism in isostructural MOFs is presented. Isocamphorate has a powerful ability to create framework topologies unexpected from common inorganic building blocks, and isocamphoric acid should allow access to hundreds of new homochiral materials.

 
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NSF-PAR ID:
10059359
Author(s) / Creator(s):
 ;  ;  ;  ;  
Publisher / Repository:
Wiley Blackwell (John Wiley & Sons)
Date Published:
Journal Name:
Angewandte Chemie International Edition
Volume:
57
Issue:
24
ISSN:
1433-7851
Page Range / eLocation ID:
p. 7101-7105
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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