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1. Electrochemical properties of Gd(III) ions in LiCl-KCl-GdCl3 at 723–1023 K

   https://doi.org/10.1016/j.jelechem.2023.117482  

   Baldivieso, Stephanie Castro; Smith, Nathan D.; Liu, Zi-Kui; Kim, Hojong (July 2023, Journal of Electroanalytical Chemistry)
2. Quantitative analysis of zero-field splitting parameter distributions in Gd( iii ) complexes

   https://doi.org/10.1039/C7CP08507A  

   Clayton, Jessica A.; Keller, Katharina; Qi, Mian; Wegner, Julia; Koch, Vanessa; Hintz, Henrik; Godt, Adelheid; Han, Songi; Jeschke, Gunnar; Sherwin, Mark S.; et al (January 2018, Physical Chemistry Chemical Physics)

   The Zero-Field Splitting (ZFS) distributions in Gd(iii) centers are accurately analyzed, with detailed discussion of error bars, and compared to the calculations with superposition model. 

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3. Magnetic properties of two Gd ^III Fe ^III ₄ metallacrowns and strategies for optimizing the magnetocaloric effect of this topology

   https://doi.org/10.1039/D1QI00207D  

   Salerno, Elvin V.; Kampf, Jeff W.; Pecoraro, Vincent L.; Mallah, Talal (May 2021, Inorganic Chemistry Frontiers)

   Two Gd III Fe III 4 metallacrown complexes are presented and analyzed for their magnetic properties. One of these species is newly identified and exhibits a bent ring geometry as opposed to the more conventional flatter conformation of the other. Both complexes are quite similar magnetically, exhibiting antiferromagnetic exchange coupling values ca . J (Fe III –N–O–Fe III ) = −7 cm −1 and J (Gd III –O–Fe III ) = −0.7 cm −1 . When analyzed for the molecular magnetocaloric effect, maximum −Δ S m values of 7.3 J K −1 kg −1 at 3 K and at 6.1 J K −1 kg −1 at 4 K were exhibited. A detailed structural-magnetic correlation is established and an assessment of several similar magnetic metallacrowns with diverse metal combinations is given with regards to their potential magnetocaloric properties. Strategies for improving the magnetocaloric properties within the Metaln + FeIII4 family of metallacrowns are proposed regarding the ratio between coupling parameters J (Fe III –N–O–Fe III )/ J (Metal n+ –O–Fe III ). 

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4. Gd ^III ‐ ¹⁹ F Distance Measurements for Proteins in Cells by Electron‐Nuclear Double Resonance

   https://doi.org/10.1002/anie.202218780  

   Seal, Manas; Zhu, Wenkai; Dalaloyan, Arina; Feintuch, Akiva; Bogdanov, Alexey; Frydman, Veronica; Su, Xun‐Cheng; Gronenborn, Angela M.; Goldfarb, Daniella (April 2023, Angewandte Chemie International Edition)

   Abstract Studies of protein structure and dynamics are usually carried out in dilute buffer solutions, conditions that differ significantly from the crowded environment in the cell. The double electron‐electron resonance (DEER) technique can track proteins’ conformations in the cell by providing distance distributions between two attached spin labels. This technique, however, cannot access distances below 1.8 nm. Here, we show that Gd^III‐¹⁹F Mims electron‐nuclear double resonance (ENDOR) measurements can cover part of this short range. Low temperature solution and in‐cell ENDOR measurements, complemented with room temperature solution and in‐cell Gd^III‐¹⁹F PRE (paramagnetic relaxation enhancement) NMR measurements, were performed on fluorinated GB1 and ubiquitin (Ub), spin‐labeled with rigid Gd^IIItags. The proteins were delivered into human cells via electroporation. The solution and in‐cell derived Gd^III‐¹⁹F distances were essentially identical and lie in the 1–1.5 nm range revealing that both, GB1 and Ub, retained their overall structure in the Gd^IIIand¹⁹F regions in the cell. 

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5. Pulsating hydrogen-deficient white dwarfs and pre-white dwarfs observed with TESS: III. Asteroseismology of the DBV star GD 358

   https://doi.org/10.1051/0004-6361/202142153  

   Córsico, A. H.; Uzundag, M.; Kepler, S. O.; Silvotti, R.; Althaus, L. G.; Koester, D.; Baran, A. S.; Bell, K. J.; Bischoff-Kim, A.; Hermes, J. J.; et al (March 2022, Astronomy & Astrophysics)

   Context. The collection of high-quality photometric data by space telescopes, such as the completed Kepler mission and the ongoing TESS program, is revolutionizing the area of white-dwarf asteroseismology. Among the different kinds of pulsating white dwarfs, there are those that have He-rich atmospheres, and they are called DBVs or V777 Her variable stars. The archetype of these pulsating white dwarfs, GD 358, is the focus of the present paper. Aims. We report a thorough asteroseismological analysis of the DBV star GD 358 (TIC 219074038) based on new high-precision photometric data gathered by the TESS space mission combined with data taken from the Earth. Methods. We reduced TESS observations of the DBV star GD 358 and performed a detailed asteroseismological analysis using fully evolutionary DB white-dwarf models computed accounting for the complete prior evolution of their progenitors. We assessed the mass of this star by comparing the measured mean period separation with the theoretical averaged period spacings of the models, and we used the observed individual periods to look for a seismological stellar model. We detected potential frequency multiplets for GD 358, which we used to identify the harmonic degree ( ℓ ) of the pulsation modes and rotation period. Results. In total, we detected 26 periodicities from the TESS light curve of this DBV star using standard pre-whitening. The oscillation frequencies are associated with nonradial g (gravity)-mode pulsations with periods from ∼422 s to ∼1087 s. Moreover, we detected eight combination frequencies between ∼543 s and ∼295 s. We combined these data with a huge amount of observations from the ground. We found a constant period spacing of 39.25 ± 0.17 s, which helped us to infer its mass ( M ⋆  = 0.588 ± 0.024  M ⊙ ) and constrain the harmonic degree ℓ of the modes. We carried out a period-fit analysis on GD 358, and we were successful in finding an asteroseismological model with a stellar mass ( M ⋆ = 0.584 −0.019 +0.025   M ⊙ ), compatible with the stellar mass derived from the period spacing, and in line with the spectroscopic mass ( M ⋆  = 0.560 ± 0.028  M ⊙ ). In agreement with previous works, we found that the frequency splittings vary according to the radial order of the modes, suggesting differential rotation. Obtaining a seismological model made it possible to estimate the seismological distance ( d seis  = 42.85 ± 0.73 pc) of GD 358, which is in very good accordance with the precise astrometric distance measured by Gaia EDR3 ( π  = 23.244 ± 0.024,  d Gaia  = 43.02 ± 0.04 pc). Conclusions. The high-quality data measured with the TESS space telescope, used in combination with data taken from ground-based observatories, provides invaluable information for conducting asteroseismological studies of DBV stars, analogously to what happens with other types of pulsating white-dwarf stars. The currently operating TESS mission, together with the advent of other similar space missions and new stellar surveys, will give an unprecedented boost to white dwarf asteroseismology. 

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