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Title: [Ru II (tpy)(bpy)Cl] + -Catalyzed reduction of carbon dioxide. Mechanistic insights by carbon-13 kinetic isotope effects
In this work, we examine the use of competitive 13 C kinetic isotope effects ( 13 C KIEs) on CO 2 reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined 13 C KIE measurements and theoretical calculations methodology for probing CO 2 conversion reactions.  more » « less
Award ID(s):
1652606
NSF-PAR ID:
10064766
Author(s) / Creator(s):
; ; ;
Date Published:
Journal Name:
Chemical Communications
ISSN:
1359-7345
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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