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  1. Ru(ii) 1,2-azolylamidino-DMSO complexes are herein described. Their electrochemical behavior in CO2media is consistent with CO2electrocatalyzed reduction, whereas photocatalytic CO2reduction experiments lead to CO and trace amounts of formate. 
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  2. We report the hydrophobicity-enhanced reactivity of Cu2+ions as an ester hydrolase. 
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    Inspired by the architecture of the macrocycle of heme d 1 , a series of synthetic mono-, di- and tri-β-oxo-substituted porphyrinoid cobalt( ii ) complexes were evaluated as electrocatalytic CO 2 reducers, identifying complexes of unusually high efficiencies in generating multi-electron reduction products, including CH 4 . 
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  7. In this work, we examine the use of competitive 13 C kinetic isotope effects ( 13 C KIEs) on CO 2 reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined 13 C KIE measurements and theoretical calculations methodology for probing CO 2 conversion reactions. 
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