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null (Ed.)Inspired by the architecture of the macrocycle of heme d 1 , a series of synthetic mono-, di- and tri-β-oxo-substituted porphyrinoid cobalt( ii ) complexes were evaluated as electrocatalytic CO 2 reducers, identifying complexes of unusually high efficiencies in generating multi-electron reduction products, including CH 4 .more » « less
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In this work, we examine the use of competitive 13 C kinetic isotope effects ( 13 C KIEs) on CO 2 reduction reactions that produce CO and formic acid as a means to formulate reaction mechanisms. The findings reported here mark a further advancement in the combined 13 C KIE measurements and theoretical calculations methodology for probing CO 2 conversion reactions.more » « less
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