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Title: Charge transfer in (PbSe) 1+δ (NbSe 2 ) 2 and (SnSe) 1+δ (NbSe 2 ) 2 ferecrystals investigated by photoelectron spectroscopy
Award ID(s):
1710214
NSF-PAR ID:
10066365
Author(s) / Creator(s):
; ; ; ; ; ;
Date Published:
Journal Name:
Journal of Physics: Condensed Matter
Volume:
30
Issue:
5
ISSN:
0953-8984
Page Range / eLocation ID:
055001
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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  1. Abstract

    The quinary members in the solid solution Hf2Fe1−δRu5−xIrx+δB2(x=1–4, VE=63–66) have been investigated experimentally and computationally. They were synthesized via arc‐melting and analyzed by EDX and X‐ray diffraction. Density functional theory (DFT) calculations predicted a preference for magnetic ordering in all members, but with a strong competition between ferro‐ and antiferromagnetism arising from interchain Fe−Fe interactions. The spin exchange and magnetic anisotropy energies predicted the lowest magnetic hardness forx=1 and 3 and the highest forx=2. Magnetization measurements confirm the DFT predictions and demonstrate that the antiferromagnetic ordering (TN=55–70 K) found at low magnetic fields changed to ferromagnetic (TC=150–750 K) at higher fields, suggesting metamagnetic behavior for all samples. As predicted, Hf2FeRu3Ir2B2has the highest intrinsic coercivity (Hc=74 kA/m) reported to date for Ti3Co5B2‐type phases. Furthermore, all coercivities outperform that of ferromagnetic Hf2FeIr5B2, indicating the importance of AFM interactions in enhancing magnetic anisotropy in these materials. Importantly, two members (x=1 and 4) maintain intrinsic coercivities in the semi‐hard range at room temperature. This study opens an avenue for controlling magnetic hardness by modulating antagonistic AFM and FM interactions in low‐dimensional rare‐earth‐free magnetic materials.

     
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  4. Abstract We report the superconductivity of the topological nodal-line semimetal candidate Sn x NbSe 2- δ with a noncentrosymmetric crystal structure. The superconducting transition temperature T c of Sn x NbSe 2- δ drastically varies with the Sn concentration x and the Se deficiency δ , and reaches 12 K, relatively higher than those of known topological superconductors. The upper critical field of this compound shows unusual temperature dependence, inconsistent with the WHH theory for conventional type-II superconductors. In a low-T c sample, the zero-temperature limit of the upper critical field parallel to the ab plane exceeds the Pauli paramagnetic limit estimated from the simple BCS weak coupling model by a factor of ∼ 2, suggestive of unusual superconductivity stabilized in Sn x NbSe 2- δ . Together with the robust superconductivity against disorder, these observations indicate that Sn x NbSe 2- δ is a promising candidate to explore topological superconductivity. 
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