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Surfaces that exhibit both superhydrophobic and superoleophobic properties have recently been demonstrated. Specifically, remarkable designs based on overhanging/inverse-trapezoidal microstructures enable water droplets to contact these surfaces only at the tips of the micro-pillars, in a state known as the Cassie state. However, the Cassie state may transition into the undesirable Wenzel state under certain conditions. Herein, we show from large-scale molecular dynamics simulations that the transition between the Cassie and Wenzel states can be controlled via precisely designed trapezoidal nanostructures on a surface. Both the base angle of the trapezoids and the intrinsic contact angle of the surface can be exploited to control the transition. For a given base angle, three regimes can be achieved: the Wenzel regime, in which water droplets can exist only in the Wenzel state when the intrinsic contact angle is less than a certain critical value; the Cassie regime, in which water droplets can exist only in the Cassie state when the intrinsic contact angle is greater than another critical value; and the bistable Wenzel–Cassie regime, in which both the Wenzel and Cassie states can exist when the intrinsic contact angle is between the two critical values. A strong base-angle dependence of the first critical value is revealed, whereas the second critical value shows much less dependence on the base angle. The stability of the Cassie state for various base angles (and intrinsic contact angles) is quantitatively evaluated by computing the free-energy barrier for the Cassie-to-Wenzel state transition.
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Small degree of anisotropic wetting on self-similar hierarchical wrinkled surfaces
We studied the wetting behavior of multiscale self-similar hierarchical wrinkled surfaces. The hierarchical surface was fabricated on poly(dimethylsiloxane) (PDMS) substrates by manipulating the sequential strain release and combined plasma/ultraviolet ozone (UVO) treatment. The generated structured surface shows an independently controlled dual-scale roughness with level-1 small-wavelength wrinkles (wavelength of 700–1500 nm and amplitude of 50–500 nm) resting on level-2 large-wavelength wrinkles (wavelength of 15–35 μm and amplitude of 3.5–5 μm), as well as accompanying orthogonal cracks. By tuning the aspect ratio of hierarchical wrinkles, the degree of wetting anisotropy in hierarchical wrinkled surfaces, defined as the contact angle difference between the parallel and perpendicular directions to the wrinkle grooves, is found to change between 3° and 9°. Through both experimental characterization (confocal fluorescence imaging) and theoretical analyses, we showed that the wetting state in the hierarchical wrinkled surface is in the Wenzel wetting state. We found that the measured apparent contact angle is larger than the theoretically predicted Wenzel contact angle, which is found to be attributed to the three-phase contact line pinning effect of both wrinkles and cracks that generates energetic barriers during the contact line motion. This is evidenced by the observed sudden drop of over 20° in the static contact angles along both perpendicular and parallel directions after slight vibration perturbation. Finally, we concluded that the observed small degree of wetting anisotropy in the hierarchical wrinkled surfaces mainly arises from the competition between orthogonal wrinkles and cracks in the contact line pinning.
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- Award ID(s):
- 1745921
- PAR ID:
- 10073039
- Date Published:
- Journal Name:
- Soft Matter
- Volume:
- 14
- Issue:
- 9
- ISSN:
- 1744-683X
- Page Range / eLocation ID:
- 1517 to 1529
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1039/C7SM02208E
