Materials combining an asymmetric pore structure with mesopores everywhere enable high surface area accessibility and fast transport, making them attractive for e.g., energy conversion and storage applications. Block copolymer (BCP)/inorganic precursor co‐assembly combined with non‐solvent induced phase separation (NIPS) provides a route to materials in which a mesoporous top surface layer merges into an asymmetric support with graded porosity along the film normal and mesopores throughout. Here, the co‐assembly and non‐solvent‐induced phase separation (CNIPS) of poly(isoprene)‐
Rotational and oscillatory shear rheometry were used to quantify the flow behavior under minimal and significant solvent evaporation conditions for polymer solutions used to fabricate isoporous asymmetric membranes by the self‐assembly and non‐solvent induced phase separation (SNIPS) method. Three different A‐B‐C triblock terpolymer chemistries of similar molar mass were evaluated: polyisoprene‐
- Award ID(s):
- 1707836
- NSF-PAR ID:
- 10073714
- Publisher / Repository:
- Wiley Blackwell (John Wiley & Sons)
- Date Published:
- Journal Name:
- Journal of Applied Polymer Science
- Volume:
- 136
- Issue:
- 6
- ISSN:
- 0021-8995
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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