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1. Isotopes to ice: Constraining provenance of glacial deposits and ice centers in west-central Gondwana

   Griffis, N.P. ; Montañez, I.P. ; Fedorchuk, N. ; Isbell, J. ; Mundil, R. ; Vesely, F. ; Weinshultz, L. ; Iannuzzi, R. ; Gulbranson, E. ; Taboada, A. ; et al ( April 2018 , Palaeogeography, palaeoclimatology, palaeoecology)

   The timing and geographic distribution of glaciers in high-latitude southern Gondwana during the Late Paleozoic Ice Age remain poorly constrained, ultimately precluding our ability to estimate ice volume and associated climate teleconnections and feedbacks during Earth's penultimate icehouse. Current aerial extents of glaciers, constrained by sedimentary flow directions, near exclusively infer paleo-glaciation to be highland-driven and may underestimate potential ice sources in continental regions from which ice sheets may have emanated. Here, we report new U-Pb ages and Hf isotope compositions of detrital zircons recovered from diamictites in two key mid- to high-latitude Gondwanan basins (Paraná, Brazil and Tepuel, Argentine Patagonia). The results indicate regional sediment sources for both basins during the early period of late Paleozoic glaciation evolving into more distal sources during the final deglaciation along southern and western Gondwana. Similar age sediment sourced from diamictites in the Congo Basin, that require an ice center in eastern Africa suggest the possibility of a large ice sheet in this area of Africa proximal to the Carboniferous-Permian boundary, which may have sourced sediments to the Paraná Basin. An inferred distal southern source of glacial sediment for the Tepuel Basin argues for the presence of an ice sheet(s) in the Ellsworth Block of Antarctica towards the end of the glaciation history in Patagonia. These findings indicate an evolution during the Late Paleozoic Ice Age from proximally to extrabasinally sourced sediment reflecting continental-scale glaciation and subsequent drainage from the Windhoek Highlands, Ellsworth Block and an east African source in west-central Gondwana. Coincidence with a long-term fall in atmospheric pCO2 during the Pennsylvanian to a minimum across the Carboniferous-Permian boundary and a subsequent rise in the early Permian suggests a primary CO2-driver for deglaciation in the Paraná Basin. Additional boundary conditions including availability of moisture and paleogeography likely further contributed to the timing of nucleation, growth and demise of these Gondwanan glaciers. 

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2. Coupled stratigraphic and U-Pb zircon age constraints on the late Paleozoic icehouse-to-greenhouse turnover in south-central Gondwana

   https://doi.org/10.1130/G46740.1  

   Griffis, Neil Patrick ; Montañez, Isabel Patricia ; Mundil, Roland ; Richey, Jon ; Isbell, John ; Fedorchuk, Nick ; Linol, Bastien ; Iannuzzi, Roberto ; Vesely, Fernando ; Mottin, Thammy ; et al ( October 2019 , Geology)

   The demise of the Late Paleozoic Ice Age has been hypothesized as diachronous, occurring first in western South America and progressing eastward across Africa and culminating in Australia over an ~60 m.y. period, suggesting tectonic forcing mechanisms that operate on time scales of 106 yr or longer. We test this diachronous deglaciation hypothesis for southwestern and south-central Gondwana with new single crystal U-Pb zircon chemical abrasion thermal ionizing mass spectrometry (CA-TIMS) ages from volcaniclastic deposits in the Paraná (Brazil) and Karoo (South Africa) Basins that span the terminal deglaciation through the early postglacial period. Intrabasinal stratigraphic correlations permitted by the new high-resolution radioisotope ages indicate that deglaciation across the south to southeast Paraná Basin was synchronous, with glaciation constrained to the Carboniferous. Cross-basin correlation reveals two additional glacial-deglacial cycles in the Karoo Basin after the terminal deglaciation in the Paraná Basin. South African glaciations were penecontemporaneous (within U-Pb age uncertainties) with third-order sequence boundaries (i.e., inferred base-level falls) in the Paraná Basin. Synchroneity between early Permian glacial-deglacial events in southwestern to south-central Gondwana and pCO2 fluctuations suggest a primary CO2 control on ice thresholds. The occurrence of renewed glaciation in the Karoo Basin, after terminal deglaciation in the Paraná Basin, reflects the secondary influences of regional paleogeography, topography, and moisture sources. 

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3. High-latitude ice and climate control on sediment supply across SW Gondwana during the late Carboniferous and early Permian

   https://doi.org/10.1130/B35852.1  

   Griffis, N. ; Montañez, I. ; Mundil, R. ; Heron, D. Le ; Dietrich, P. ; Kettler, C. ; Linol, B. ; Mottin, T. ; Vesely, F. ; Iannuzzi, R. ; et al ( February 2021 , GSA Bulletin)

   null (Ed.)

   Abstract The response of sediment routing to climatic changes across icehouse-to-greenhouse turnovers is not well documented in Earth's pre-Cenozoic sedimentary record. Southwest Gondwana hosts one of the thickest and most laterally extensive records of Earth's penultimate icehouse, the late Paleozoic ice age. We present the first high-resolution U-Pb zircon chemical abrasion–isotope dilution–thermal ionization mass spectrometry (CA-ID-TIMS) analysis of late Paleozoic ice age deposits in the Kalahari Basin of southern Africa, which, coupled with existing CA-ID-TIMS zircon records from the Paraná and Karoo Basins, we used to refine the late Paleozoic ice age glacial history of SW Gondwana. Key findings from this work suggest that subglacial evidence in the Kalahari region is restricted to the Carboniferous (older than 300 Ma), with glacially influenced deposits culminating in this region by the earliest Permian (296 Ma). The U-Pb detrital zircon geochronologic records from the Paraná Basin of South America, which was located downstream of the Kalahari Basin in the latest Carboniferous and Permian, indicate that large-scale changes in sediment supplied to the Paraná were contemporaneous with shifts in the SW Gondwana ice record. Gondwanan deglaciation events were associated with the delivery of far-field, African-sourced sediments into the Paraná Basin. In contrast, Gondwanan glacial periods were associated with the restriction of African-sourced sediments into the basin. We interpret the influx of far-field sediments into the Paraná Basin as an expansion of the catchment area for the Paraná Basin during the deglaciation events, which occurred in the latest Carboniferous (300–299 Ma), early Permian (296 Ma), and late early Permian (<284 Ma). The coupled ice and detrital zircon records for this region of Gondwana present opportunities to investigate climate feedbacks associated with changes in freshwater and nutrient delivery to late Paleozoic ocean basins across the turnover from icehouse to greenhouse conditions. 

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4. A Carboniferous apex for the late Paleozoic icehouse

   https://doi.org/10.1144/sp535-2022-256  

   Griffis, N. ; Mundil, R. ; Montañez, I. ; Le Heron, D. ; Dietrich, P. ; Iannuzzi, R. ( October 2022 , Geological Society, London, Special Publications)

   Icehouse climate systems occur across an abbreviated portion of Earth history, constitutingc.25% of the Phanerozoic record. The Late Paleozoic Ice Age (LPIA) was the most extreme and longest lasting glaciation of the Phanerozoic and is characterized by periods of acute continental-scale glaciation, separated by periods of ice minima or ice-free conditions on the order of <10⁶years. The late Paleozoic glaciogenic record of the Paraná and Kalahari basins of southern Gondwana form one of the largest, best-preserved and well-calibrated records of this glaciation. In the Carboniferous, the eastern and southern margins of the Paraná Basin and the Kalahari Basin were characterized by subglacial conditions, with evidence for continental and upland glaciers. In the latest Carboniferous, these basins transitioned from subglacial reservoirs to ice-free or ‘ice distal‘ conditions evidenced by the widespread deposition of marine deposits juxtaposed on subglacial bedforms. High-precision U–Pb zircon chemical abrasion thermal ionization mass spectrometry geochronological constraints from volcanic ash deposits in the deglacial marine black shales of the Kalahari Basin and from fluvial and coal successions, which overlie marine deposits in the Paraná Basin, indicate subglacial evidence in these regions is constrained to the Carboniferous. The loss of ice in these regions is congruent with a late Carboniferous peak inpCO₂and widespread marine anoxia in the late Carboniferous. The permeant retreat of glaciers in basinal settings, despite an early PermianpCO₂nadir, highlights the influence of short-term perturbations on the longer-term CO₂record and suggests an ice threshold had been crossed in the latest Carboniferous. A definitive driver for greenhouse gases in the LPIA, such as abundant and sustained volcanic activity or an increased biological pump driven by ocean fertilization, is unresolved for this period. Lastly, the proposed Carboniferous apex for the high-latitude LPIA record is incongruent with observations from the low-latitude tropics where an early Permian peak is proposed.

    

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5. Spatiotemporal variability of the late Paleozoic glacial-to-postglacial transition across eastern Paraná Basin, Brazil

   https://doi.org/10.1016/j.sedgeo.2023.106420  

   Mottin, T.E. ; Vesely, F.F. ; Iannuzzi, R. ; Griffis, N.P. ; Montañez, I.P. ( July 2023 , Sedimentary Geology)

   The late Paleozoic glacial-to-postglacial turnover evolved complexly across Gondwana. Successions bearing volcaniclastic material that can be radiometrically dated provide crucial information about the timing of those climate events. The southernmost part of the Paraná Basin, for instance, has a high-precision geochronological framework. The eastern sector of this basin (Paraná State and north of Santa Catarina State), however, lacks radiometric ages, but conversely, has a more complete stratigraphic record, and paleontological information still poorly explored for the purpose of biostratigraphic correlation. This work examines the glacial-to-postglacial interval in the Paraná State, represented by the upper Itararé Group (Taciba Formation; glacial) and lower–middle Rio Bonito Formation (postglacial). Sedimentological, paleontological and geochemical data from outcrops, cores and well logs were used to decipher the timing, paleoclimatic and paleogeographic scenarios of this transition. The examined succession comprises four stacked units (U1 to U4, from older to younger). Diamictite-dominated units (U1 and U3), here interpreted as consecutive glaciation–deglaciation events, are separated by non-glacial, continental to shallow marine deposits, commonly bearing fossil plants and coal seams (U2). An important transgression followed the first deglaciation,which is equivalent to the “Eurydesma transgression”, basedonthepresence of marine invertebrates of the homonymous fauna in the Passinho Shale. U2 holds elements of two different floras, i.e., Phyllotheca–Gangamopteris (P–G), predating the “Eurydesma transgression”, and Glossopteris Brasilodendron (G–B), above the transgression. Therefore, U2 is interpreted as an interglacial interval, once it records a climate improving before the last glacial episode of U3, which is further supported by relatively high values of the Chemical Index of Alteration (CIA). Deposits of U3, associated with a decrease in the value of the CIA, are unconformably overlain by U4. The occurrence of coal-bearing postglacial facies (U4) associated with the G–B Flora, coincides with an increase in the CIA values. Sediment transport was toward the SWin all units and in the same direction it is observed an overall thinning of U1 and U3 and thickening of U2. The interglacial P–G Flora of the study area correlates with postglacial southernmost floras, based on U–Pb CA-TIMS Asselian ages of tonsteins. Correlation of the Eurydesma fauna-containing Passinho Shale with equivalent successions with high-precision age control in southern Africa, allowed us to position both deglaciations of the Taciba Formation (U1 and U3) in the Asselian. These findings suggest that U1 and U3 record two early Permian glacial episodes, with the younger one (U3) disappearing southward. Accordingly, our results indicate that the glacial-to-postglacial turnoverwas diachronous along the eastern belt of the Paraná Basin, being progressively older southward, considering that interglacial fossil plant assemblages in the eastern margin correspond in time to postglacial assemblages farther south. 

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