skip to main content

Explore Research Products in the NSF-PAR

Title: Isotopes to ice: Constraining provenance of glacial deposits and ice centers in west-central Gondwana
The timing and geographic distribution of glaciers in high-latitude southern Gondwana during the Late Paleozoic Ice Age remain poorly constrained, ultimately precluding our ability to estimate ice volume and associated climate teleconnections and feedbacks during Earth's penultimate icehouse. Current aerial extents of glaciers, constrained by sedimentary flow directions, near exclusively infer paleo-glaciation to be highland-driven and may underestimate potential ice sources in continental regions from which ice sheets may have emanated. Here, we report new U-Pb ages and Hf isotope compositions of detrital zircons recovered from diamictites in two key mid- to high-latitude Gondwanan basins (Paraná, Brazil and Tepuel, Argentine Patagonia). The results indicate regional sediment sources for both basins during the early period of late Paleozoic glaciation evolving into more distal sources during the final deglaciation along southern and western Gondwana. Similar age sediment sourced from diamictites in the Congo Basin, that require an ice center in eastern Africa suggest the possibility of a large ice sheet in this area of Africa proximal to the Carboniferous-Permian boundary, which may have sourced sediments to the Paraná Basin. An inferred distal southern source of glacial sediment for the Tepuel Basin argues for the presence of an ice sheet(s) in the Ellsworth Block of Antarctica towards the end of the glaciation history in Patagonia. These findings indicate an evolution during the Late Paleozoic Ice Age from proximally to extrabasinally sourced sediment reflecting continental-scale glaciation and subsequent drainage from the Windhoek Highlands, Ellsworth Block and an east African source in west-central Gondwana. Coincidence with a long-term fall in atmospheric pCO2 during the Pennsylvanian to a minimum across the Carboniferous-Permian boundary and a subsequent rise in the early Permian suggests a primary CO2-driver for deglaciation in the Paraná Basin. Additional boundary conditions including availability of moisture and paleogeography likely further contributed to the timing of nucleation, growth and demise of these Gondwanan glaciers.  more » « less
Award ID(s):
1728705
NSF-PAR ID:
10074180
Author(s) / Creator(s):
; ; ; ; ; ; ; ; ; ; ; ; ; ; ;
Date Published:
Journal Name:
Palaeogeography, palaeoclimatology, palaeoecology
ISSN:
1872-616X
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
More Like this
  1. ; ; ; ; ; ; ; ; ; ; et al ( , GSA Bulletin)
    null (Ed.)
    Abstract The response of sediment routing to climatic changes across icehouse-to-greenhouse turnovers is not well documented in Earth's pre-Cenozoic sedimentary record. Southwest Gondwana hosts one of the thickest and most laterally extensive records of Earth's penultimate icehouse, the late Paleozoic ice age. We present the first high-resolution U-Pb zircon chemical abrasion–isotope dilution–thermal ionization mass spectrometry (CA-ID-TIMS) analysis of late Paleozoic ice age deposits in the Kalahari Basin of southern Africa, which, coupled with existing CA-ID-TIMS zircon records from the Paraná and Karoo Basins, we used to refine the late Paleozoic ice age glacial history of SW Gondwana. Key findings from this work suggest that subglacial evidence in the Kalahari region is restricted to the Carboniferous (older than 300 Ma), with glacially influenced deposits culminating in this region by the earliest Permian (296 Ma). The U-Pb detrital zircon geochronologic records from the Paraná Basin of South America, which was located downstream of the Kalahari Basin in the latest Carboniferous and Permian, indicate that large-scale changes in sediment supplied to the Paraná were contemporaneous with shifts in the SW Gondwana ice record. Gondwanan deglaciation events were associated with the delivery of far-field, African-sourced sediments into the Paraná Basin. In contrast, Gondwanan glacial periods were associated with the restriction of African-sourced sediments into the basin. We interpret the influx of far-field sediments into the Paraná Basin as an expansion of the catchment area for the Paraná Basin during the deglaciation events, which occurred in the latest Carboniferous (300–299 Ma), early Permian (296 Ma), and late early Permian (<284 Ma). The coupled ice and detrital zircon records for this region of Gondwana present opportunities to investigate climate feedbacks associated with changes in freshwater and nutrient delivery to late Paleozoic ocean basins across the turnover from icehouse to greenhouse conditions. 
    more » « less
  2. ; ; ; ; ; ( , Geological Society, London, Special Publications)
    Abstract

    Icehouse climate systems occur across an abbreviated portion of Earth history, constitutingc.25% of the Phanerozoic record. The Late Paleozoic Ice Age (LPIA) was the most extreme and longest lasting glaciation of the Phanerozoic and is characterized by periods of acute continental-scale glaciation, separated by periods of ice minima or ice-free conditions on the order of <106years. The late Paleozoic glaciogenic record of the Paraná and Kalahari basins of southern Gondwana form one of the largest, best-preserved and well-calibrated records of this glaciation. In the Carboniferous, the eastern and southern margins of the Paraná Basin and the Kalahari Basin were characterized by subglacial conditions, with evidence for continental and upland glaciers. In the latest Carboniferous, these basins transitioned from subglacial reservoirs to ice-free or ‘ice distal‘ conditions evidenced by the widespread deposition of marine deposits juxtaposed on subglacial bedforms. High-precision U–Pb zircon chemical abrasion thermal ionization mass spectrometry geochronological constraints from volcanic ash deposits in the deglacial marine black shales of the Kalahari Basin and from fluvial and coal successions, which overlie marine deposits in the Paraná Basin, indicate subglacial evidence in these regions is constrained to the Carboniferous. The loss of ice in these regions is congruent with a late Carboniferous peak inpCO2and widespread marine anoxia in the late Carboniferous. The permeant retreat of glaciers in basinal settings, despite an early PermianpCO2nadir, highlights the influence of short-term perturbations on the longer-term CO2record and suggests an ice threshold had been crossed in the latest Carboniferous. A definitive driver for greenhouse gases in the LPIA, such as abundant and sustained volcanic activity or an increased biological pump driven by ocean fertilization, is unresolved for this period. Lastly, the proposed Carboniferous apex for the high-latitude LPIA record is incongruent with observations from the low-latitude tropics where an early Permian peak is proposed.

     
    more » « less
  3. ( , Revista del Museo de La Plata)
    The Late Paleozoic Ice Age (LPIA) was one of Earth’s most extreme climatic events where sea level and biotic restructuring were driven by linked oscillations in the climate system. Despite an evolving understanding of the ice age, the size, distribution, paleogeography, timing, depositional settings, and possible bipolarity of the glaciation remains unresolved. However, new and refined radioisotopic age dates are revising the timing and extent of individual stages of the ice age. Recent studies suggest numerous, ice centers fluctuated diachronously as glaciation shifted across Gondwana. The LPIA began in the Famennian in northern South America and Africa and ended in eastern Australia during the Wuchiapingian. Although glaciation was widespread, numerous ice-free areas occurred adjacent to major glacial centers. Deglaciation was also diachronous beginning in the Bashkirian in western Argentina, shifting to the Paraná Basin by the end of the Pennsylvanian, with deglaciation of the South Polar Region occurring during the late Early Permian. Deglaciation culminated in eastern Australia with the disappearance of high, mid-latitude, alpine glaciers during the Wuchiapingian at a time when Polar Gondwana was ice-free. Recent work on diamictites in northeastern Russia indicates that these strata were not glacigenic but instead were deposited as volcanic debris flows and slides/slumps associated with concurrent activity in the Okhotsk-Taigonos volcanic arc. Therefore, bipolar glaciation cannot be confirmed. Although fluctuations in greenhouse gases were a major driver of climate, paleogeography, tectonism, and other minor drivers also played a role in the nucleation and disappearance of LPIA glaciers. 
    more » « less
  4. ; ; ; ; ; ; ; ; ; ; et al ( , Geology)
    The demise of the Late Paleozoic Ice Age has been hypothesized as diachronous, occurring first in western South America and progressing eastward across Africa and culminating in Australia over an ~60 m.y. period, suggesting tectonic forcing mechanisms that operate on time scales of 106 yr or longer. We test this diachronous deglaciation hypothesis for southwestern and south-central Gondwana with new single crystal U-Pb zircon chemical abrasion thermal ionizing mass spectrometry (CA-TIMS) ages from volcaniclastic deposits in the Paraná (Brazil) and Karoo (South Africa) Basins that span the terminal deglaciation through the early postglacial period. Intrabasinal stratigraphic correlations permitted by the new high-resolution radioisotope ages indicate that deglaciation across the south to southeast Paraná Basin was synchronous, with glaciation constrained to the Carboniferous. Cross-basin correlation reveals two additional glacial-deglacial cycles in the Karoo Basin after the terminal deglaciation in the Paraná Basin. South African glaciations were penecontemporaneous (within U-Pb age uncertainties) with third-order sequence boundaries (i.e., inferred base-level falls) in the Paraná Basin. Synchroneity between early Permian glacial-deglacial events in southwestern to south-central Gondwana and pCO2 fluctuations suggest a primary CO2 control on ice thresholds. The occurrence of renewed glaciation in the Karoo Basin, after terminal deglaciation in the Paraná Basin, reflects the secondary influences of regional paleogeography, topography, and moisture sources. 
    more » « less
  5. ; ; ; ; ; ; ; ; ; ( , Palaeogeography, palaeoclimatology, palaeoecology)
    The location, longevity, and geographic extent of late Paleozoic ice centers in west-central Gondwana remain ambiguous. Paleovalleys on the Rio Grande do Sul Shield of southernmost Brazil have previously been interpreted as fjords carved by outlet glaciers that originated in Africa and emptied into the Paraná Basin (Brazil). In this study, the sedimentology, stratigraphy, and provenance of sediments infilling two such paleovalleys (the Mariana Pimentel and Leão paleovalleys) were examined in order to test the hypothesis that an ice center over present day Namibia drained across southernmost Brazil during the Carboniferous and Permian. Contrary to previous findings, the facies assemblage from within the paleovalleys is inconsistent with a fjord setting and no clear evidence for glaciation was observed. The facies show a transition from a non-glacial lacustrine/estuarine environment, to a fluvial-dominated setting, and finally to a restricted marine/estuarine environment. Detrital zircon results present a single population of Neoproterozoic ages (c. 800–550 Ma) from the paleovalley fill that matches the ages of underlying igneous and metamorphic basement (Dom Feliciano Belt) and is incongruent with African sources that contain abundant older (Mesoproterozoic, Paleoproterozoic, and Archean) zircons. Furthermore, results suggest that the formation of the paleovalleys and the deposition of their fill were controlled by the reactivation of Neoproterozoic basement structures during the Carboniferous and Permian. The lack of evidence for glaciation in these paleovalleys highlights the need for detailed studies of supposed late Paleozoic glacial deposits. These results are supportive of the hypothesis that well-established glacial sediments on the Rio Grande do Sul Shield (southern margin of the Paraná Basin) may be the product of a separate lobe extending north across Uruguay, rather than a single, massive ice sheet draining west from Africa. 
    more » « less
  • Citation Formats
  • MLA
  • APA
  • Chicago
  • BibTeX
  • Save / Share this Record
  • Send to Email