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1. Geochemically distinct carbon isotope distributions in Allochromatium vinosum DSM 180 ^T grown photoautotrophically and photoheterotrophically

   https://doi.org/10.1111/gbi.12221  

   Tang, T.; Mohr, W.; Sattin, S. R.; Rogers, D. R.; Girguis, P. R.; Pearson, A. (March 2017, Geobiology)
2. Free‐breathing simultaneous T ₁ , T ₂ , and T ₂ ^∗ quantification in the myocardium

   https://doi.org/10.1002/mrm.28753  

   Hermann, Ingo; Kellman, Peter; Demirel, Omer B.; Akçakaya, Mehmet; Schad, Lothar R.; Weingärtner, Sebastian (September 2021, Magnetic Resonance in Medicine)
3. Determination of Block Copolymer Micelle Core T _g Using ¹ H NMR Transverse ( T ₂ ) Relaxation Measurements of Micelle Coronas

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   Fesenmeier, Daniel J; Kim, Hyun Chang; Kim, Seyoung; Won, You-Yeon (November 2023, Macromolecules)
4. Ynamide and Azaalleneyl. Acid‐Base Promoted Chelotropic and Spin‐State Rearrangements in a Versatile Heterocumulene [(Ad)NCC( ^t Bu)] ⁻

   https://doi.org/10.1002/anie.202401433  

   Russell, John_B; Jafari, Mehrafshan_G; Kim, Jun‐Hyeong; Pudasaini, Bimal; Ozarowski, Andrew; Telser, Joshua; Baik, Mu‐Hyun; Mindiola, Daniel_J (April 2024, Angewandte Chemie International Edition)

   Abstract We introduce the heterocumulene ligand [(Ad)NCC(^tBu)]⁻(Ad=1‐adamantyl (C₁₀H₁₅),^tBu=tert‐butyl, (C₄H₉)), which can adopt two forms, the azaalleneyl and ynamide. This ligand platform can undergo a reversible chelotropic shift using Brønsted acid‐base chemistry, which promotes an unprecedented spin‐state change of the [V^III] ion. These unique scaffolds are prepared via addition of 1‐adamantyl isonitrile (C≡NAd) across the alkylidyne in complexes [(BDI)V≡C^tBu(OTf)] (A) (BDI⁻=ArNC(CH₃)CHC(CH₃)NAr), Ar=2,6‐ⁱPr₂C₆H₃) and [(dBDI)V≡C^tBu(OEt₂)] (B) (dBDI²⁻=ArNC(CH₃)CHC(CH₂)NAr). ComplexAreacts with C≡NAd, to generate the high‐spin [V^III] complex with a κ¹‐N‐ynamide ligand, [(BDI)V{κ¹‐N‐(Ad)NCC(^tBu)}(OTf)] (1). Conversely,Breacts with C≡NAd to generate a low‐spin [V^III] diamagnetic complex having a chelated κ²‐C,N‐azaalleneyl ligand, [(dBDI)V{κ²‐N,C‐(Ad)NCC(^tBu)}] (2). Theoretical studies have been applied to better understand the mechanism of formation of2and the electronic reconfiguration upon structural rearrangement by the alteration of ligand denticity between1and2. 

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5. Precursor-directed biosynthesis of catechol compounds in Acinetobacter bouvetii DSM 14964

   https://doi.org/10.1039/D0CC04171H  

   Reitz, Zachary L.; Butler, Alison (October 2020, Chemical Communications)

   null (Ed.)

   Genome mining for VibH homologs reveals several species of Acinetobacter with a gene cluster that putatively encodes the biosynthesis of catechol siderophores with an amine core. A. bouvetii DSM 14964 produces three novel biscatechol siderophores: propanochelin ( 1 ), butanochelin ( 2 ), and pentanochelin ( 3 ). This strain has a relaxed specificity for the amine substrate, allowing for the biosynthesis of a variety of non-natural siderophore analogs by precursor directed biosynthesis. Of potential synthetic utility, A. bouvetii DSM 14964 condenses 2,3-dihydroxybenzoic acid (2,3-DHB) to allylamine and propargylamine, producing catecholic compounds which bind iron( iii ) and may be further modified via thiol–ene or azide–alkyne click chemistry. 

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