A model for optical gain in colloidal nanoplatelets
Cadmium chalcogenide nanoplatelets (NPLs) and their heterostructures have been reported to have low gain thresholds and large gain coefficients, showing great potential for lasing applications. However, the further improvement of the optical gain properties of NPLs is hindered by a lack of models that can account for their optical gain characteristics and predict their dependence on the properties (such as lateral size, concentration, and/or optical density). Herein, we report a systematic study of optical gain (OG) in 4-monolayer thick CdSe NPLs by both transient absorption spectroscopy study of colloidal solutions and amplified spontaneous emission (ASE) measurement of thin films. We showed that comparing samples with the same optical density at the excitation, the OG threshold is not dependent of the NPL lateral area, while the saturation gain amplitude is dependent on the NPL lateral area when comparing samples with the same optical density at the excitation wavelength. Both the OG and ASE thresholds increase with the optical density at the excitation wavelength for samples of the same NPL thickness and lateral area. We proposed an OG model for NPLs that can successfully account for the observed lateral area and optical density dependences. The model reveals that OG originates from stimulated more »
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Publication Date:
NSF-PAR ID:
10076465
Journal Name:
Chemical Science
Volume:
9
Issue:
3
Page Range or eLocation-ID:
728 to 734
ISSN:
2041-6520
4. We demonstrate for the first time, to our knowledge, the occurrence of asixth-order exceptional point of degeneracy (EPD) in a realistic multimode optical photonic structure by using a modified periodic coupled-resonator optical waveguide (CROW) at the optical wavelength$λ<#comment/>e=1550nm$. The sixth-order EPD is obtained in a CROW without the need of loss or gain, and such an EPD corresponds to a very special band edge of the periodic photonic structure where six eigenmodes coalesce, so we refer to it as the sixth-order degenerate band edge (6DBE). Moreover, we report a new scaling law of the quality factor$Q$of an optical cavity made of such a periodic 6DBE-CROW with cavity length as$Q∝<#comment/>N7$, when operating near the 6DBE with$N$being the number of unit cells in the periodic finite-length CROW. Furthermore, we elaborate on the application of the 6DBE to ultralow-threshold lasers. We present a novel scaling law of the lasing threshold that scales as$N−<#comment/>7$when operating near the 6DBE. Also, we show the superiority of the threshold scaling of the 6DBE-CROW to the scaling of another CROW with the same size operating near a fourth-order EPD that is often referred to asmore »