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The electrocatalytic carbon dioxide reduction reaction (CO 2 RR) to produce valuable fuels and chemicals with renewable energy inputs is an attractive route to convert intermittent green energy sources ( e.g. , solar and wind) to chemical energy, alleviate our dependence on fossil fuels, and simultaneously reduce net carbon dioxide emission. However, the generation of reduced multi-carbon products with high energy density and wide applicability from the CO 2 RR, such as oxygenates and hydrocarbons, suffers from high overpotential, slow reaction rate, and low selectivity due to its intrinsic multi-electron transfer nature. Moreover, the involved anodic oxygen evolution reaction (OER) also requires large overpotential and its product O 2 bears limited economic value. The potentially generated reactive oxygen species (ROS) during the OER may also degrade the membrane of a CO 2 reduction electrolyzer. Herein, we review the recent progress in novel integrated strategies to address the aforementioned challenges in the electrocatalytic CO 2 RR. These innovative strategies include (1) concurrent CO 2 electroreduction via co-feeding additional chemicals besides CO 2 gas, (2) tandem CO 2 electroreduction utilizing other catalysts for converting the in situ formed products from the CO 2 RR into more valuable chemicals, and (3) hybrid CO 2 electroreduction through integrating thermodynamically more favourable organic upgrading reactions to replace the anodic OER. We specifically highlight these novel integrated electrolyzer designs instead of focusing on nanostructured engineering of various electrocatalysts, in the hope of inspiring others to approach CO 2 electroreduction from a holistic perspective. The current challenges and future opportunities of electrocatalytic CO 2 reduction will also be discussed at the end.
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