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1. Direct Online Mass Spectrometry Measurements of Ice Nucleating Particles at a California Coastal Site

   https://doi.org/10.1029/2019JD030466  

   Cornwell, G. C. ; McCluskey, C. S. ; Levin, E. J. T. ; Suski, K. J. ; DeMott, P. J. ; Kreidenweis, S. M. ; Prather, K. A. ( November 2019 , Journal of Geophysical Research: Atmospheres)

   The formation of ice in clouds can strongly impact cloud properties and precipitation processes during storms, including atmospheric rivers. Sea spray aerosol (SSA) particles are relatively inefficient as ice nucleating particles (INPs) compared to mineral dust. However, due to the vast coverage of the Earth's surface by the oceans, a number of recent studies have focused on identifying sources of marine INPs, particularly in regions lacking a strong influence from dust. This study describes the integration, validation, and application of a system coupling a continuous flow diffusion chamber with a single particle mass spectrometer using a pumped counterflow virtual impactor to remove nonnucleated particles and selectively measure the composition of INPs with a detection efficiency of 3.10×10⁻⁴. In situ measurements of immersion freezing INP composition were made at a coastal site in California using the integrated system. Mineral dust particles were the most abundant ice crystal residual type during the sampling period and found to be ice active despite having undergone atmospheric processing. SSA were more abundant in ambient measurements but represented only a minor fraction of the ice crystal residual population at −31 °C. Notably, the SSA particles that activated were enriched with organic nitrogen species that were likely transferred from the ocean. Calculations of ice nucleation active site densities were within good agreement with previous studies of mineral dust and SSA.

    

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2. Spatial and temporal variability of snowfall over Greenland from CloudSat observations

   https://doi.org/10.5194/acp-19-8101-2019  

   Bennartz, Ralf ; Fell, Frank ; Pettersen, Claire ; Shupe, Matthew D. ; Schuettemeyer, Dirk ( January 2019 , Atmospheric Chemistry and Physics)

   Abstract. We use the CloudSat 2006–2016 data record to estimate snowfall over theGreenland Ice Sheet (GrIS). We first evaluate CloudSat snowfall retrievalswith respect to remaining ground-clutter issues. Comparing CloudSatobservations to the GrIS topography (obtained from airborne altimetrymeasurements during IceBridge) we find that at the edges of the GrISspurious high-snowfall retrievals caused by ground clutter occasionallyaffect the operational snowfall product. After correcting for this effect,the height of the lowest valid CloudSat observation is about 1200 mabove the local topography as defined by IceBridge. We then use ground-based millimeter wavelength cloud radar (MMCR) observations obtained from the Integrated Characterization of Energy, Clouds, Atmospheric state, and Precipitation at Summit, Greenland (ICECAPS) experiment to devise a simple,empirical correction to account for precipitation processes occurringbetween the height of the observed CloudSat reflectivities and the snowfallnear the surface. Using the height-corrected, clutter-cleared CloudSatreflectivities we next evaluate various Z–S relationships in terms ofsnowfall accumulation at Summit through comparison with weekly stake fieldobservations of snow accumulation available since 2007. Using a set of threeZ–S relationships that best agree with the observed accumulation at Summit,we then calculate the annual cycle snowfall over the entire GrIS as well asover different drainage areas and compare the derived mean values and annualcycles of snowfall to ERA-Interim reanalysis. We find the annual meansnowfall over the GrIS inferred from CloudSat to be 34±7.5 cm yr⁻¹liquid equivalent (where the uncertainty is determined by the range invalues between the three different Z–S relationships used). In comparison,the ERA-Interim reanalysis product only yields 30 cm yr⁻¹ liquid equivalentsnowfall, where the majority of the underestimation in the reanalysisappears to occur in the summer months over the higher GrIS and appears to berelated to shallow precipitation events. Comparing all available estimatesof snowfall accumulation at Summit Station, we find the annually averagedliquid equivalent snowfall from the stake field to be between 20 and 24 cm yr⁻¹, depending on the assumed snowpack density and from CloudSat 23±4.5 cm yr⁻¹. The annual cycle at Summit is generally similar betweenall data sources, with the exception of ERA-Interim reanalysis, which showsthe aforementioned underestimation during summer months.

    

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3. Ejection of Dust From the Ocean as a Potential Source of Marine Ice Nucleating Particles

   https://doi.org/10.1029/2020JD033073  

   Cornwell, Gavin C. ; Sultana, Camille M. ; Prank, Marje ; Cochran, Richard E. ; Hill, Thomas C. J. ; Schill, Gregory P. ; DeMott, Paul J. ; Mahowald, Natalie ; Prather, Kimberly A. ( December 2020 , Journal of Geophysical Research: Atmospheres)

   Oceans are, generally, relatively weak sources of ice nucleating particles (INPs). Thus, dust transported from terrestrial regions can dominate atmospheric INP concentrations even in remote marine regions. Studies of ocean‐emitted INPs have focused upon sea spray aerosols containing biogenic species. Even though large concentrations of dust are transported over marine regions, resuspended dust has never been explicitly considered as another possible source of ocean‐emitted INPs. Current models assume that deposited dust is not re‐emitted from surface waters. Our laboratory studies of aerosol particles produced from coastal seawater and synthetic seawater doped with dust show that dust can indeed be ejected from water during bubble bursting. INP concentration measurements show these ejected dust particles retain ice nucleating activity. Doping synthetic seawater to simulate a strong dust deposition event produced INPs active at temperatures colder than −13°C and INP concentrations 1 to 2 orders of magnitude greater than either lab sea spray or marine boundary layer measurements. The relevance of these laboratory findings is highlighted by single‐particle composition measurements along the Californian coast where at least 9% of dust particles were mixed with sea salt. Additionally, global modeling studies show that resuspension of dust from the ocean could exert the most impact over the Southern Ocean, where ocean‐emitted INPs are thought to dominate atmospheric INP populations. More work characterizing the factors governing the resuspension of dust particles is required to understand the potential impact upon clouds.

    

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4. Toward autonomous surface-based infrared remote sensing of polar clouds: cloud-height retrievals

   https://doi.org/10.5194/amt-9-3641-2016  

   Rowe, Penny M. ; Cox, Christopher J. ; Walden, Von P. ( January 2016 , Atmospheric Measurement Techniques)

   Abstract. Polar regions are characterized by their remoteness, making measurements challenging, but an improved knowledge of clouds and radiation is necessary to understand polar climate change. Infrared radiance spectrometers can operate continuously from the surface and have low power requirements relative to active sensors. Here we explore the feasibility of retrieving cloud height with an infrared spectrometer that would be designed for use in remote polar locations. Using a wide variety of simulated spectra of mixed-phase polar clouds at varying instrument resolutions, retrieval accuracy is explored using the CO₂ slicing/sorting and the minimum local emissivity variance (MLEV) methods. In the absence of imposed errors and for clouds with optical depths greater than  ∼ 0.3, cloud-height retrievals from simulated spectra using CO₂ slicing/sorting and MLEV are found to have roughly equivalent high accuracies: at an instrument resolution of 0.5cm⁻¹, mean biases are found to be  ∼ 0.2km for clouds with bases below 2 and −0.2km for higher clouds. Accuracy is found to decrease with coarsening resolution and become worse overall for MLEV than for CO₂ slicing/sorting; however, the two methods have differing sensitivity to different sources of error, suggesting an approach that combines them. For expected errors in the atmospheric state as well as both instrument noise and bias of 0.2mW/(m²srcm⁻¹), at a resolution of 4cm⁻¹, average retrieval errors are found to be less than  ∼ 0.5km for cloud bases within 1km of the surface, increasing to  ∼ 1.5km at 4km. This sensitivity indicates that a portable, surface-based infrared radiance spectrometer could provide an important complement in remote locations to satellite-based measurements, for which retrievals of low-level cloud are challenging.

    

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5. Detecting the permafrost carbon feedback: talik formation and increased cold-season respiration as precursors to sink-to-source transitions

   https://doi.org/10.5194/tc-12-123-2018  

   Parazoo, Nicholas C. ; Koven, Charles D. ; Lawrence, David M. ; Romanovsky, Vladimir ; Miller, Charles E. ( January 2018 , The Cryosphere)

   Abstract. Thaw and release of permafrost carbon (C) due to climate change is likely tooffset increased vegetation C uptake in northern high-latitude (NHL)terrestrial ecosystems. Models project that this permafrost C feedback mayact as a slow leak, in which case detection and attribution of the feedbackmay be difficult. The formation of talik, a subsurface layer of perenniallythawed soil, can accelerate permafrost degradation and soil respiration,ultimately shifting the C balance of permafrost-affected ecosystems fromlong-term C sinks to long-term C sources. It is imperative to understand andcharacterize mechanistic links between talik, permafrost thaw, andrespiration of deep soil C to detect and quantify the permafrost C feedback.Here, we use the Community Land Model (CLM) version 4.5, a permafrost andbiogeochemistry model, in comparison to long-term deep borehole data alongNorth American and Siberian transects, to investigate thaw-driven C sourcesin NHL (>55^∘N) from 2000 to 2300. Widespread talik at depth isprojected across most of the NHL permafrost region(14million km²) by 2300, 6.2million km² of which isprojected to become a long-term C source, emitting 10Pg C by 2100,50Pg C by 2200, and 120Pg C by 2300, with few signs ofslowing. Roughly half of the projected C source region is in predominantlywarm sub-Arctic permafrost following talik onset. This region emits only20Pg C by 2300, but the CLM4.5 estimate may be biased low by notaccounting for deep C in yedoma. Accelerated decomposition of deep soilC following talik onset shifts the ecosystem C balance away from surfacedominant processes (photosynthesis and litter respiration), butsink-to-source transition dates are delayed by 20–200 years by highecosystem productivity, such that talik peaks early (∼2050s, although boreholedata suggest sooner) and C source transition peaks late(∼2150–2200). The remaining C source region in cold northern Arcticpermafrost, which shifts to a net source early (late 21st century), emits5 times more C (95Pg C) by 2300, and prior to talik formation dueto the high decomposition rates of shallow, young C in organic-rich soilscoupled with low productivity. Our results provide important clues signalingimminent talik onset and C source transition, including (1) late cold-season(January–February) soil warming at depth (∼2m),(2) increasing cold-season emissions (November–April), and (3) enhancedrespiration of deep, old C in warm permafrost and young, shallow C in organic-rich cold permafrost soils. Our results suggest a mosaic of processes thatgovern carbon source-to-sink transitions at high latitudes and emphasize theurgency of monitoring soil thermal profiles, organic C age and content, cold-season CO₂ emissions, andatmospheric ¹⁴CO₂ as key indicatorsof the permafrost C feedback.

    

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