More Like this

1. Regional and Local Stratigraphic Markers in Three Hudson River Cores Taken Near Peekskill, New York: Core LWB 4-5

   Abdul, B. ; Adeghe, S. ; Diallo, M. B. ; McCann, B. ; Abbott, D. H. ; Bostick, B. C. ; Chang, C. ; Block, K. A. ( December 2018 , American Geophysical Union, Fall Meeting 2018, abstract #B53I-2167)

   We have been studying the stratigraphy of core LWB 4-5 taken in 2001 in the Hudson River 1.5 km north of the transit of the Peekskill meteorite in October 1992. We measured magnetic susceptibility and elemental composition at 1 cm intervals down to 50 cm and then at 5 cm intervals down to 108 cm. Magnetic susceptibilities are unusually high (above 20 cgs units) from 12-19 cm and again at 31 cm. The level at 31 cm contains mm-sized fragments of Fe oxide. X-Ray Fluorescence spectroscopy revealed high Ni/Cr levels concentrated from 9-11 cm and again below 97 cm. We found tektite-like spheroids, dumbbells and teardrops from 8-15 cm depth. They are glasses and they contain appreciable K, consistent with an origin as true tektites but we have not identified the source. Overall, we interpret the high susceptibility, high Ni/Cr and possibly tektite bearing layer as a resulting from the fall of one of the bodies postulated to have fallen with the Peekskill meteorite in 1992. A 1992 age for the top of the Peekskill layer at 8-9 cm depth is consistent with a uniform sedimentation rate in the core and the occurrence of the base of modern Pb atmore »97 cm depth. From previous work on cores from Central Park Lake, the base of modern Pb represents the year 1880 A.D. We also found other prominent horizons whose ages fit a linear sedimentation rate model. We found a step change in As/Pb ratio whose inferred age matches 1988, the year when Pb and Cu arsenide were banned as pesticides. Our core exhibits peaks in Ca and Sr content and a minor susceptibility peak at 17.5 depth that may represent the 1980 "Great Catskill Toilet Flush" Hudson River flood event. The Catskills contain abundant marine limestone that could serve as a source for Ca and Sr. A prominent susceptibility peak at 37.5 cm could represent a flood in 1955. We also found a peak in Pb at 50 cm depth whose inferred age matches that of the cessation of incinerator burning in 1938. 137Cs and 210Pb ages are in progress and may be available by the time of the meeting. The high Pb and As levels in parts of LWB 4-5 are supported by examination of the coarse fraction. We found two bright orange grains, both with carbon rich coatings. One grain analyses on the X-ray analyzer of an SEM as 8%C, 70% Pb, 17%As and 2% Cu. The second grain analyzes as 10% C, 43% Pb, 1% Ca, 2% P, 27% As, 4% Fe, 2% Ni, 1% Si, and 6% Zn. All analyses are in wt.% on an oxygen free basis.« less
2. Regional and Local Stratigraphic Markers in Three Hudson River Cores Taken Near Peekskill, New York: LWB4-3

   McCann, B. ; Abbott, D. H. ; Bostick, B. C. ; Diallo, M. B. ; Abdul, B. ; Adeghe, S. ( December 2018 , American Geophysical Union, Fall Meeting 2018, abstract #B53I-2172)

   We have been studying the stratigraphy of core LWB4-3 taken in 2001 in the Hudson River near Peekskill New York along the transit path of the Peekskill meteorite. We measured magnetic susceptibility at 1 cm intervals down to 108 cm and chemical composition at 1 cm intervals down to 192 cm. The highest magnetic susceptibility occurs at 18 cm depth. This inferred Peekskill meteorite layer with high magnetic susceptibility contains locally higher concentrations of Ni and higher Ni/Cr ratios. Our identification of the high susceptibility, high Ni layer as coming from the fall of the Peekskill meteorite in 1991 is consistent with a uniform sedimentation rate in the core and the occurrence of the base of modern Pb at > 192 cm depth (below the base of the core). From previous work on cores from Central Park Lake, the base of modern Pb represents the year 1880 A.D. We also found other prominent horizons whose ages fit a linear sedimentation rate model. We found a peak in As, whose inferred age matches 1988, the year when Pb and Cu arsenide were banned as pesticides. In addition, we found a modest susceptibility peak above the Peekskill layer whose inferred age matchesmore »that of the 1996 Hudson River flood. We found a second modest susceptibility peak below the Peekskill layer whose inferred age matches that of the "Great Catskill Toilet Flush Flood" in 1980. This layer also has local maxima in Pb, Cu and Ca. The Catskills contain Devonian limestone that might be the source of excess Ca. Copper Mine brook is located on the east bank of the Hudson north of Peekskill and is a potential source of Cu during floods. Our core exhibits a distinct increase in Ca content starting at 20 cm depth and increasing towards the top of the core. This prominent increase in Ca may represent 1991 A.D, the time of the invasion of the zebra mussel. We are testing this depth range for calcium carbonate to determine if the upward calcium increase could be from the invasion of the zebra mussel, increased soil erosion or anthropogenic pollution. We found a peak in Pb at 112 cm depth whose inferred age matches that of the cessation of incinerator burning in 1938. Cs-137 and Pb-210 ages are in progress and may be available by the time of the meeting. We also saw an unusual horizon at a depth of 118 cm with a high peak of Cr. This would be approximately the year 1936, which corresponds to a large flood in the Hudson.« less
3. Florida mangrove saltmarsh reference surface soils

   https://doi.org/10.6073/pasta/0e08cbe07c84488cb7b9dd16669946d0  

   Lewis, David Bruce ( January 2021 )

   Abstract

   Site description. This data package consists of data obtained from sampling surface soil (the 0-7.6 cm depth profile) in black mangrove (Avicennia germinans) dominated forest and black needlerush (Juncus roemerianus) saltmarsh along the Gulf of Mexico coastline in peninsular west-central Florida, USA. This location has a subtropical climate with mean daily temperatures ranging from 15.4 °C in January to 27.8 °C in August, and annual precipitation of 1336 mm. Precipitation falls as rain primarily between June and September. Tides are semi-diurnal, with 0.57 m median amplitudes during the year preceding sampling (U.S. NOAA National Ocean Service, Clearwater Beach, Florida, station 8726724). Sea-level rise is 4.0 ± 0.6 mm per year (1973-2020 trend, mean ± 95 % confidence interval, NOAA NOS Clearwater Beach station). The A. germinans mangrove zone is either adjacent to water or fringed on the seaward side by a narrow band of red mangrove (Rhizophora mangle). A near-monoculture of J. roemerianus is often adjacent to and immediately landward of the A. germinans zone. The transition from the mangrove to the J. roemerianus zone is variable in our study area. An abrupt edge between closed-canopy mangrove and J. roemerianus monoculture may extend for up to several hundred meters in some locations, while other stretches of ecotone present a gradual transition where smaller, widely spaced trees are interspersed into the herbaceous marsh. Juncus roemerianus then extends landward to a high marsh patchwork of succulent halophytes (including Salicornia bigellovi, Sesuvium sp., and Batis maritima), scattered dwarf mangrove, and salt pans, followed in turn by upland vegetation that includes Pinus sp. and Serenoa repens. Field design and sample collection. We established three study sites spaced at approximately 5 km intervals along the western coastline of the central Florida peninsula. The sites consisted of the Salt Springs (28.3298°, -82.7274°), Energy Marine Center (28.2903°, -82.7278°), and Green Key (28.2530°, -82.7496°) sites on the Gulf of Mexico coastline in Pasco County, Florida, USA. At each site, we established three plot pairs, each consisting of one saltmarsh plot and one mangrove plot. Plots were 50 m^2 in size. Plots pairs within a site were separated by 230-1070 m, and the mangrove and saltmarsh plots composing a pair were 70-170 m apart. All plot pairs consisted of directly adjacent patches of mangrove forest and J. roemerianus saltmarsh, with the mangrove forests exhibiting a closed canopy and a tree architecture (height 4-6 m, crown width 1.5-3 m). Mangrove plots were located at approximately the midpoint between the seaward edge (water-mangrove interface) and landward edge (mangrove-marsh interface) of the mangrove zone. Saltmarsh plots were located 20-25 m away from any mangrove trees and into the J. roemerianus zone (i.e., landward from the mangrove-marsh interface). Plot pairs were coarsely similar in geomorphic setting, as all were located on the Gulf of Mexico coastline, rather than within major sheltering formations like Tampa Bay, and all plot pairs fit the tide-dominated domain of the Woodroffe classification (Woodroffe, 2002, "Coasts: Form, Process and Evolution", Cambridge University Press), given their conspicuous semi-diurnal tides. There was nevertheless some geomorphic variation, as some plot pairs were directly open to the Gulf of Mexico while others sat behind keys and spits or along small tidal creeks. Our use of a plot-pair approach is intended to control for this geomorphic variation. Plot center elevations (cm above mean sea level, NAVD 88) were estimated by overlaying the plot locations determined with a global positioning system (Garmin GPS 60, Olathe, KS, USA) on a LiDAR-derived bare-earth digital elevation model (Dewberry, Inc., 2019). The digital elevation model had a vertical accuracy of ± 10 cm (95 % CI) and a horizontal accuracy of ± 116 cm (95 % CI). Soil samples were collected via coring at low tide in June 2011. From each plot, we collected a composite soil sample consisting of three discrete 5.1 cm diameter soil cores taken at equidistant points to 7.6 cm depth. Cores were taken by tapping a sleeve into the soil until its top was flush with the soil surface, sliding a hand under the core, and lifting it up. Cores were then capped and transferred on ice to our laboratory at the University of South Florida (Tampa, Florida, USA), where they were combined in plastic zipper bags, and homogenized by hand into plot-level composite samples on the day they were collected. A damp soil subsample was immediately taken from each composite sample to initiate 1 y incubations for determination of active C and N (see below). The remainder of each composite sample was then placed in a drying oven (60 °C) for 1 week with frequent mixing of the soil to prevent aggregation and liberate water. Organic wetland soils are sometimes dried at 70 °C, however high drying temperatures can volatilize non-water liquids and oxidize and decompose organic matter, so 50 °C is also a common drying temperature for organic soils (Gardner 1986, "Methods of Soil Analysis: Part 1", Soil Science Society of America); we accordingly chose 60 °C as a compromise between sufficient water removal and avoidance of non-water mass loss. Bulk density was determined as soil dry mass per core volume (adding back the dry mass equivalent of the damp subsample removed prior to drying). Dried subsamples were obtained for determination of soil organic matter (SOM), mineral texture composition, and extractable and total carbon (C) and nitrogen (N) within the following week. Sample analyses. A dried subsample was apportioned from each composite sample to determine SOM as mass loss on ignition at 550 °C for 4 h. After organic matter was removed from soil via ignition, mineral particle size composition was determined using a combination of wet sieving and density separation in 49 mM (3 %) sodium hexametaphosphate ((NaPO_3)_6) following procedures in Kettler et al. (2001, Soil Science Society of America Journal 65, 849-852). The percentage of dry soil mass composed of silt and clay particles (hereafter, fines) was calculated as the mass lost from dispersed mineral soil after sieving (0.053 mm mesh sieve). Fines could have been slightly underestimated if any clay particles were burned off during the preceding ignition of soil. An additional subsample was taken from each composite sample to determine extractable N and organic C concentrations via 0.5 M potassium sulfate (K_2SO_4) extractions. We combined soil and extractant (ratio of 1 g dry soil:5 mL extractant) in plastic bottles, reciprocally shook the slurry for 1 h at 120 rpm, and then gravity filtered it through Fisher G6 (1.6 μm pore size) glass fiber filters, followed by colorimetric detection of nitrite (NO_2^-) + nitrate (NO_3^-) and ammonium (NH_4^+) in the filtrate (Hood Nowotny et al., 2010,Soil Science Society of America Journal 74, 1018-1027) using a microplate spectrophotometer (Biotek Epoch, Winooski, VT, USA). Filtrate was also analyzed for dissolved organic C (referred to hereafter as extractable organic C) and total dissolved N via combustion and oxidation followed by detection of the evolved CO_2 and N oxide gases on a Formacs HT TOC/TN analyzer (Skalar, Breda, The Netherlands). Extractable organic N was then computed as total dissolved N in filtrate minus extractable mineral N (itself the sum of extractable NH_4-N and NO_2-N + NO_3-N). We determined soil total C and N from dried, milled subsamples subjected to elemental analysis (ECS 4010, Costech, Inc., Valencia, CA, USA) at the University of South Florida Stable Isotope Laboratory. Median concentration of inorganic C in unvegetated surface soil at our sites is 0.5 % of soil mass (Anderson, 2019, Univ. of South Florida M.S. thesis via methods in Wang et al., 2011, Environmental Monitoring and Assessment 174, 241-257). Inorganic C concentrations are likely even lower in our samples from under vegetation, where organic matter would dilute the contribution of inorganic C to soil mass. Nevertheless, the presence of a small inorganic C pool in our soils may be counted in the total C values we report. Extractable organic C is necessarily of organic C origin given the method (sparging with HCl) used in detection. Active C and N represent the fractions of organic C and N that are mineralizable by soil microorganisms under aerobic conditions in long-term soil incubations. To quantify active C and N, 60 g of field-moist soil were apportioned from each composite sample, placed in a filtration apparatus, and incubated in the dark at 25 °C and field capacity moisture for 365 d (as in Lewis et al., 2014, Ecosphere 5, art59). Moisture levels were maintained by frequently weighing incubated soil and wetting them up to target mass. Daily CO_2 flux was quantified on 29 occasions at 0.5-3 week intervals during the incubation period (with shorter intervals earlier in the incubation), and these per day flux rates were integrated over the 365 d period to compute an estimate of active C. Observations of per day flux were made by sealing samples overnight in airtight chambers fitted with septa and quantifying headspace CO_2 accumulation by injecting headspace samples (obtained through the septa via needle and syringe) into an infrared gas analyzer (PP Systems EGM 4, Amesbury, MA, USA). To estimate active N, each incubated sample was leached with a C and N free, 35 psu solution containing micronutrients (Nadelhoffer, 1990, Soil Science Society of America Journal 54, 411-415) on 19 occasions at increasing 1-6 week intervals during the 365 d incubation, and then extracted in 0.5 M K_2SO_4 at the end of the incubation in order to remove any residual mineral N. Active N was then quantified as the total mass of mineral N leached and extracted. Mineral N in leached and extracted solutions was detected as NH_4-N and NO_2-N + NO_3-N via colorimetry as above. This incubation technique precludes new C and N inputs and persistently leaches mineral N, forcing microorganisms to meet demand by mineralizing existing pools, and thereby directly assays the potential activity of soil organic C and N pools present at the time of soil sampling. Because this analysis commences with disrupting soil physical structure, it is biased toward higher estimates of active fractions. Calculations. Non-mobile C and N fractions were computed as total C and N concentrations minus the extractable and active fractions of each element. This data package reports surface-soil constituents (moisture, fines, SOM, and C and N pools and fractions) in both gravimetric units (mass constituent / mass soil) and areal units (mass constituent / soil surface area integrated through 7.6 cm soil depth, the depth of sampling). Areal concentrations were computed as X × D × 7.6, where X is the gravimetric concentration of a soil constituent, D is soil bulk density (g dry soil / cm^3), and 7.6 is the sampling depth in cm.
   More>>
4. What we can learn in the kitchen sink: an example from garnet granulite

   Stowell, H.H. ( January 2021 , America Geophysical Union)

   Interpretation of geochronological and petrological data from partially-melted granulite is challenging. However, integration of multiple chronometers and mineral assemblage diagrams (MAD) can be used to estimate the nature and duration of processes. Excellent lower-crustal exposures of garnet granulite from the Malaspina Pluton, Fiordland New Zealand provide an ideal place to employ this kitchen sink approach. We use zircon U-Pb ages from LA-ICPMS, SHRIMP-RG, and CA-TIMS, garnet Lu-Hf and Sm-Nd ages, and MAD in order to evaluate local partial melting vs. melt injection, equilibrium volumes, P-T conditions, and the duration of lower crustal thermal events. Host diorite (H), garnet-clinopyroxene reaction zones (GRZ), coarse garnet selvages, and tonalite veins provide a record of intrusion and granulite facies partial melting. Zircon U-Pb ages range from 123 to 107 Ma (all); LA-ICPMS ages contain the entire range; CA-TIMS ages range from 118.30±0.13 to 115.7±0.18 Ma; and SHRIMP-RG ages range from 121.4±2 to 109.8±1.8 Ma. The latter two techniques are interpreted to indicate primary igneous crystallization from ~119 to ~116 Ma and the youngest ~110 Ma ages are interpreted as metamorphic zircon growth. Garnet ages for ~1 cm grains are ~113 Ma (Lu-Hf & Sm-Nd) and record metamorphic growth, and <0.3 mm grains with Sm-Ndmore »ages from 113 to 104 Ma reflect high temperature intracrystalline diffusion and isotopic closure during cooling to amphibolite facies. Zircon trace-element compositions indicate 2 distinct crystallization trends reflecting evolution of primary magma batches. MAD indicate that garnet was not in equilibrium with sampled rock compositions. Instead, garnet shows apparent equilibrium with a modeled mixture of the GRZ and the H and grew in equilibrium with an effective bulk composition that shifted toward the leucosome. This would produce the observed increase in garnet grossular content. We conclude that: Malaspina rocks from Crooked Arm preserve evidence for 2 igneous layers which evolved as discrete magmas, igneous crystallization lasted 2 to 3 m.y., granulite metamorphism peaked ~ 3 m.y. after intrusion, metamorphism lasted ≥3 m.y., cooling occurred at ~20°C/m.y., and granulite minerals equilibrated with a mixture of solid phases and melt at ~14 kbar and 920°C (based on garnet compositions and MAD).« less
5. The ST22 chronology for the Skytrain Ice Rise ice core – Part 1: A stratigraphic chronology of the last 2000 years

   https://doi.org/10.5194/cp-18-1831-2022  

   Hoffmann, Helene M. ; Grieman, Mackenzie M. ; King, Amy C. ; Epifanio, Jenna A. ; Martin, Kaden ; Vladimirova, Diana ; Pryer, Helena V. ; Doyle, Emily ; Schmidt, Axel ; Humby, Jack D. ; et al ( January 2022 , Climate of the Past)

   Abstract. A new ice core was drilled in West Antarctica on Skytrain Ice Rise in field season 2018/2019. This 651 m ice core is one of the main targets of the WACSWAIN (WArm Climate Stability of the West Antarctic ice sheet in the last INterglacial) project. A present-day accumulation rate of 13.5 cm w.e. yr−1 was derived. Although the project mainly aims to investigate the last interglacial (115–130 ka), a robust chronology period covering the recent past is needed to constrain the age models for the deepest ice. Additionally, this time period is important for understanding current climatic changes in the West Antarctic region. Here, we present a stratigraphic chronology for the top 184.14 m of the Skytrain ice core based on absolute age tie points interpolated using annual layer counting encompassing the last 2000 years of climate history. Together with a model-based depth–age relationship of the deeper part of the ice core, this will form the ST22 chronology. The chemical composition, dust content, liquid conductivity, water isotope concentration and methane content of the whole core was analysed via continuous flow analysis (CFA) at the British Antarctic Survey. Annual layer counting was performed by manual counting of seasonal variations in mainly the sodium and calcium records. Thismore »counted chronology was informed and anchored by absolute age tie points, namely, the tritium peak (1965 CE) and six volcanic eruptions. Methane concentration variations were used to further constrain the counting error. A minimal error of ±1 year at the tie points was derived, accumulating to ± 5 %–10 % of the age in the unconstrained sections between tie points. This level of accuracy enables data interpretation on at least decadal timescales and provides a solid base for the dating of deeper ice, which is the second part of the chronology.« less