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Title: A Family of A-Site Cation-Deficient Double-Perovskite-Related Iridates: Ln 9 Sr 2 Ir 4 O 24 (Ln = La, Pr, Nd, Sm)
Award ID(s):
1655740
PAR ID:
10092159
Author(s) / Creator(s):
; ;
Date Published:
Journal Name:
Inorganic Chemistry
Volume:
57
Issue:
13
ISSN:
0020-1669
Page Range / eLocation ID:
7797 to 7804
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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    Abstract Heat capacities and enthalpies of formation of BaGd2O4were determined by high‐temperature differential scanning calorimetry and high‐temperature oxide melt solution calorimetry, respectively. Thermodynamic stability of BaLn2O4compounds increases with decreasing Ln3+ionic radius. Previously reported data on BaNd2O4and BaSm2O4corroborate this trend. Missing data for compounds in BaO–Ln2O3(Ln = La, Pr, Eu, Er) systems were estimated from established relations, thermodynamic assessment was performed, and binary phase diagrams were calculated. 
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