More Like this

1. Versatility of Tellurium in Heteroanionic Ln ₂ O ₂ Te (Ln = La, Ce, Pr) and Tellurate Ln ₂ TeO ₆ (Ln = La, Pr)

   https://doi.org/10.1021/acs.inorgchem.2c02287  

   Orr, Melissa S.; Cruz, Katheryn R.; Nguyen, Hoa H.; Kojima, Akari L.; Macaluso, Robin T. (November 2022, Inorganic Chemistry)
2. Assessing the 4f Orbital Participation in the Ln–C Bonds of [Li(THF) ₄ ][Ln(C ₆ Cl ₅ ) ₄ ] (Ln = La, Ce)

   https://doi.org/10.1021/acs.inorgchem.2c02304  

   Ordoñez, Osvaldo; Yu, Xiaojuan; Wu, Guang; Autschbach, Jochen; Hayton, Trevor W. (September 2022, Inorganic Chemistry)
3. Thermodynamic assessment of BaO–Ln ₂ O ₃ (Ln = La, Pr, Eu, Gd, Er) systems

   https://doi.org/10.1111/jace.17060  

   Gong, Weiping; Liu, Yanzhi; Xie, Yun; Zhao, Zhenting; Ushakov, Sergey V.; Navrotsky, Alexandra (February 2020, Journal of the American Ceramic Society)

   Abstract Heat capacities and enthalpies of formation of BaGd₂O₄were determined by high‐temperature differential scanning calorimetry and high‐temperature oxide melt solution calorimetry, respectively. Thermodynamic stability of BaLn₂O₄compounds increases with decreasing Ln³⁺ionic radius. Previously reported data on BaNd₂O₄and BaSm₂O₄corroborate this trend. Missing data for compounds in BaO–Ln₂O₃(Ln = La, Pr, Eu, Er) systems were estimated from established relations, thermodynamic assessment was performed, and binary phase diagrams were calculated. 

   more » « less
4. Mechanochemical Syntheses of Ln(hfac) ₃ (H ₂ O) _x (Ln = La-Sm, Tb): Isolation of 10-, 9-, and 8-Coordinate Ln(hfac) _n Complexes

   https://doi.org/10.1021/acs.inorgchem.2c01274  

   Chappidi, Deepthi Y.; Gordon, Matthew N.; Ashberry, Hannah M.; Huang, Junjie; Labedis, Bruce M.; Cooper, Riley E.; Cooper, Brandon J.; Carta, Veronica; Skrabalak, Sara E.; Dunbar, Kim R.; et al (July 2022, Inorganic Chemistry)
5. From Ln ₂ O ₂ S to Ln ₁₀ OS ₁₄ : exploring the sulphur spectrum of trivalent lanthanoid oxysulphides

   https://doi.org/10.1039/D4DT00294F  

   Wuille_Bille, Brian A; Velázquez, Jesús M (April 2024, Dalton Transactions)

   Lanthanoid oxysulphides exhibit great versatility in their chemical compositions which allow for their optoelectronic properties to be tuned by the relative amounts of oxygen and sulphur present in their crystal structures. 

   more » « less