In classical electrokinetics, the electrophoretic velocity of a dielectric particle is a linear function of the applied electric field. Theoretical studies have predicted the onset of nonlinear electrophoresis at high electric fields because of the nonuniform surface conduction over the curved particle. However, experimental studies have been left behind and are insufficient for a fundamental understanding of the parametric effects on nonlinear electrophoresis. We present in this work a systematic experimental study of the effects of buffer concentration, particle size, and particle zeta potential on the electrophoretic velocity of polystyrene particles in a straight rectangular microchannel for electric fields of up to 3 kV/cm. The measured nonlinear electrophoretic particle velocity is found to exhibit a 2(±0.5)‐order dependence on the applied electric field, which appears to be within the theoretically predicted 3‐ and 3/2‐order dependences for low and high electric fields, respectively. Moreover, the obtained nonlinear electrophoretic particle mobility increases with decreasing buffer concentration (for the same particle) and particle size (for particles with similar zeta potentials) or increasing particle zeta potential (for particles with similar sizes). These observations are all consistent with the theoretical predictions for high electric fields.
Initiation of Streamers Due to Hydrometeor Collisions in Thunderclouds
In order to initiate streamers and leaders under thunderstorm conditions the electric field should reach values higher than the critical breakdown field Ek (i.e., similar to 30 kV/cm/atm. However, the maximum electric field in thunderstorms measured by balloons is similar to 6-9 kV/cm/atm. In present work, to achieve the electric field amplification required for streamer initiation, a system of two approaching spherical hydrometeors is investigated. Streamer initiation is determined from a Meek number, describing electron multiplication in fields above Ek. We have found the relationships between radii of particles for successful streamer initiation in the gap between these two particles and also on the outside periphery of the two-particle system when the particles are connected by a discharge channel. Furthermore, we estimated the frequency of streamer initiation using three realistic hydrometeor size model distributions available in the literature and found that the scenario of streamer initiation on the outside periphery is only possible for relatively high electric fields >= 0.5Ek at altitudes of 3 and 6 km.
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- Award ID(s):
- 1744099
- NSF-PAR ID:
- 10095068
- Date Published:
- Journal Name:
- Journal of Geophysical Research: Atmospheres
- Volume:
- 123
- ISSN:
- 2169-897X
- Page Range / eLocation ID:
- 7050-7064
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
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Abstract -
Presented here is the first continuous separation of microparticles and cells of similar characteristics employing linear and nonlinear electrokinetic phenomena in an insulator-based electrokinetic (iEK) system. By utilizing devices with insulating features, which distort the electric field distribution, it is possible to combine linear and nonlinear EK phenomena, resulting in highly effective separation schemes that leverage the new advancements in nonlinear electrophoresis. This work combines mathematical modeling and experimentation to separate four distinct binary mixtures of particles and cells. A computational model with COMSOL Multiphysics was used to predict the retention times (tR,p) of the particles and cells in iEK devices. Then, the experimental separations were carried out using the conditions identified with the model, where the experimental retention time (tR,e) of the particles and cells was measured. A total of four distinct separations of binary mixtures were performed by increasing the level of difficulty. For the first separation, two types of polystyrene microparticles, selected to mimic Escherichia coli and Saccharomyces cerevisiae cells, were separated. By leveraging the knowledge gathered from the first separation, a mixture of cells of distinct domains and significant size differences, E. coli and S. cerevisiae, was successfully separated. The third separation also featured cells of different domains but closer in size: Bacillus cereus versus S. cerevisiae. The last separation included cells in the same domain and genus, B. cereus versus Bacillus subtilis. Separation results were evaluated in terms of number of plates (N) and separation resolution (Rs), where Rs values for all separations were above 1.5, illustrating complete separations. Experimental results were in agreement with modeling results in terms of retention times, with deviations in the 6–27% range, while the variation between repetitions was between 2 and 18%, demonstrating good reproducibility. This report is the first prediction of the retention time of cells in iEK systems.more » « less
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Abstract Streamers play a key role in the formation and propagation of lightning channels. In nature streamers rarely appear alone. Their ensemble behavior is very complex and challenging to describe. For instance, the intricate dynamics within the streamer zone of negative lightning leaders give rise to space stems, which help advance the stepped-leader. Another example is how the increasing morphological complexity of sprites can lead to higher sprite current and greater energy deposition in the mesosphere. Insights into the complex dynamics of a streamer corona can be obtained from laboratory experiments that allow us to control the conditions of streamer formation. Based on simultaneous nanosecond-temporal-resolution photography, and measurements of voltage, current, and x-ray emissions, we report the characteristics of negative laboratory streamers in 88 kPa of atmosphere. The streamers are produced at peak voltages of 62.2 ± 3.8 kV in a point-to-plane discharge gap of 6 cm. While all discharges were driven to the same peak voltage, the discharges occurred at different stages of the relatively slow voltage rise (177 ns), allowing us to study discharge properties as a function of onset voltage. The onset voltage ranged between 24 and 67 kV, but x-ray emissions were observed to only occur above 53 kV, with x-ray burst energies scaling quadratically with voltage. The average delay between the current pulse and x-ray emission was found to be 3.5 ± 0.5 ns, indicating that runaway electrons are produced during the streamer inception phase or no later than the transition stage, when the inception cloud is breaking into streamer filaments. During this short time span, runaway electrons can traverse the gap, hit the ground plate and produce bremsstrahlung x-ray photons. However, streamers themselves cannot traverse more than 3.5 mm across the gap, which supports the idea that runaway electron production is not associated to streamer connection to the ground electrode.more » « less
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null (Ed.)The manner of sample injection is critical in microscale electrokinetic (EK) separations, as the resolution of a separation greatly depends on sample quality and how the sample is introduced into the system. There is a significant wealth of knowledge on the development of EK injection methodologies that range from simple and straightforward approaches to sophisticated schemes. The present study focused on the development of optimized EK sample injection schemes for direct current insulator-based EK (DC-iEK) systems. These are microchannels that contain arrays of insulating structures; the presence of these structures creates a nonuniform electric field distribution when a potential is applied, resulting in enhanced nonlinear EK effects. Recently, it was reported that the nonlinear EK effect of electrophoresis of the second kind plays a major role in particle migration in DC-iEK systems. This study presents a methodology for designing EK sample injection schemes that consider the nonlinear EK effects exerted on the particles being injected. Mathematical modeling with COMSOL Multiphysics was employed to identify proper voltages to be used during the EK injection process. Then, a T-microchannel with insulating posts was employed to experimentally perform EK injection and separate a sample containing two types of similar polystyrene particles. The quality of the EK injections was assessed by comparing the resolution (Rs) and number of plates (N) of the experimental particle separations. The findings of this study establish the importance of considering nonlinear EK effects when planning for successful EK injection schemes.more » « less
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Abstract Coupon specimens of poled and depoled lead zirconate titanate (PZT) are examined under combined stress wave and electric loading conditions. Mode‐I crack initiation and fracture behavior is examined using ultrahigh‐speed imaging and two‐dimensional digital image correlation. The dynamic critical stress intensity factor (
) is extracted using measured displacement fields ahead of the impulsively loaded crack tip, and compared between poled and depoled plates that were either under no electric field, positive 0.46 kV/mm electric field, or negative 0.46 kV/mm electric field. Poled specimens had a poling direction and applied electric field direction normal to the crack front. The addition of an electric field resulted in a crack‐enhancing effect, where the dynamic fracture toughness of poled specimens under 0.46 kV/mm was almost half that of samples with no electric field. Depoled samples experienced almost no change in dynamic fracture toughness with the addition of an electric field.
- Free Publicly Accessible Full Text
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Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.1029/2018JD028407
