Synthesis and Characterization of Non-Isolated-Pentagon-Rule Actinide Endohedral Metallofullerenes U@ C 1 (17418)-C 76 , U@ C 1 (28324)-C 80 , and Th@ C 1 (28324)-C 80 : Low-Symmetry Cage Selection Directed by a Tetravalent Ion
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Light induced charge separation in a newly synthesized triphenylamine–thiophene-Sc 3 N@ I h -C 80 donor–acceptor conjugate and its C 60 analog, triphenylamine–thiophene-C 60 conjugate is reported, and the significance of the thiophene spacer in promoting electron transfer events is unraveled.