The interface characteristics of the matrix and fibers significantly influence the evolution of residual stress in composite materials. In this study, we provide a methodology for reducing the residual stress in laminated composites by modifying the thermomechanical properties at the fiber–matrix interface. A hydrothermal chemical growth method was used to grow Zinc Oxide nanowires on the carbon fibers. We then utilized a novel digital image correlation approach to evaluate strains and residual stresses, in situ, throughout the autoclave curing of composites. We find that interface modification results in the reduction of residual stress and an increase in laminate strength and stiffness. Upon growing ZnO NWs on the carbon fibers, the maximum in situ in-plane strain components were reduced by approximately 55% and 31%, respectively, while the corresponding maximum residual stresses were decreased by 50.8% and 49.33% for the cross-play laminate [0°/90°] layup in the x and y directions, respectively. For the [45°/-45°] angle ply layup in the x-direction, the strain was decreased by 27.3%, and the maximum residual stress was reduced by 41.5%, whereas in the y-direction, the strain was decreased by 166.3%, and the maximum residual stress was reduced by 17.8%. Furthermore, mechanical testing revealed that the tensile strength for the [45°/-45°] and [0°/90°] laminates increased by 130% and 20%, respectively, with the interface modification.
more »
« less
Optical Properties and Mechanical Modeling of Acetylated Transparent Wood Composite Laminates
Transparent wood composites (TWCs) are a new class of light-transmitting wood-based materials composed of a delignified wood template that is infiltrated with a refractive- index-matched polymer resin. Recent research has focused primarily on the fabrication and characterization of single-ply TWCs. However, multi-ply composite laminates are of interest due to the mechanical advantages they impart compared to the single ply. In this work, 1- and 2-ply [0°/90°] TWC laminates were fabricated using a delignified wood template (C) and an acetylated delignified wood template (AC). The optical and mechanical properties of resultant C and AC TWC laminates were determined using ultraviolet-visible spectroscopy (UV-Vis) and tensile testing (5× replicates), respectively. In addition, the ability of classical lamination plate theory and simple rule of mixtures to predict multi-ply tensile modulus and strength, respectively, from ply-level mechanical properties were investigated and are reported herein. Experimental results highlight tradeoffs that exist between the mechanical and optical responses of both unmodified and chemically modified TWCs. Template acetylation reduced the stiffness and strength in the 0° fiber direction by 2.4 GPa and 58.9 MPa, respectively, compared to the unmodified samples. At high wavelengths of light (>515 nm), AC samples exhibited higher transmittance than the C samples. Above 687 nm, the 2-ply AC sample exhibited a higher transmittance than the 1-ply C sample, indicating that thickness-dependent optical constraints can be overcome with improved interfacial interactions. Finally, both predictive models were successful in predicting the elastic modulus and tensile strength response for the 2-ply C and AC samples.
more »
« less
- Award ID(s):
- 1537194
- NSF-PAR ID:
- 10106895
- Date Published:
- Journal Name:
- Materials
- Volume:
- 12
- Issue:
- 14
- ISSN:
- 1996-1944
- Page Range / eLocation ID:
- 2256
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
more » « less
Low‐temperature compounding of natural fiber/thermoplastic composites via solid‐state shear pulverization (SSSP) is explored for the first time, with a goal of processing temperature‐sensitive natural fibers with high temperature‐melting engineering thermoplastics without fiber degradation. The model study was based on polyamide 6 (PA6) as the matrix material and short flax fibers as the filler materials; flax fiber type was varied to provide a range of comparison. Composite structural characterization was conducted using computer tomography, optical microscopy, and scanning electron microscopy, while mechanical property measurements were performed on injection molded specimens in both tension and bending. SSSP demonstrated robust and effective processing results in model PA6/flax composites, especially when compared with conventional extrusion. SSSP was able to isolate unmodified scutched fibers into individual elementary fibers with minimal scission, and effectively distribute them in the polymer matrix
in situ . The dispersed and distributed filler morphology led to mechanical property enhancements, including 230% and 40% increases in Young's modulus and tensile strength, respectively, compared with neat PA6, at a 20 vol% fiber content. POLYM. COMPOS., 40:3285–3295, 2019. © 2018 Society of Plastics Engineers -
more » « less
ABSTRACT Cellulose nanocrystal (CNCs)‐reinforced poly(lactic acid) (PLA) nanocomposites were prepared using twin screw extrusion followed by injection molding. Masterbatch approach was used to achieve more efficient dispersion of CNCs in PLA matrix. Modified CNCs (b‐CNCs) were prepared using benzoic acid as a nontoxic material through a green esterification method in a solvent‐free technique. Transmission electron microscopy images did not exhibit significant differences in the structure of b‐CNCs as compared with unmodified CNCs. However, a reduction of 6.6–15.5% in the aspect ratio of b‐CNCs was observed. The fracture surface of PLA‐b‐CNCs nanocomposites exhibited rough and irregular pattern which confirmed the need of more energy for fracture. Pristine CNCs showed a decrease in the thermal stability of nanocomposites, however, b‐CNCs nanocomposites exhibited higher thermal stability than pure PLA. The average storage modulus was improved by 38 and 48% by addition of CNCs and b‐CNCs in PLA, respectively. The incorporation of b‐CNCs increased Young's modulus, ultimate tensile stress, elongation at break, and impact strength by 27.02, 10.90, 4.20, and 32.77%, respectively, however, CNCs nanocomposites exhibited a slight decrease in ultimate strength and elongation at break. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci.
2018 ,135 , 46468. -
more » « less
The transverse tensile strength of composites is susceptible to size effects. Therefore, it is paramount to develop length-scale specific physical test procedures to validate computational models that estimate the transverse composite response using micromechanics. To this end, a computational process modeling and virtual mechanical testing framework are presented in this study to predict the transverse response of composite microstructures subjected to processing conditions. Informed by a comprehensive material dataset, the numerical model is shown to reliably predict the process-induced residual stress generation in composite microstructures and accurately evaluate its influence on their transverse strength prediction. A novel procedure to fabricate thin composite laminates from a single ply of carbon fibers and characterize their transverse tensile response is presented to validate the numerical model. The results show excellent agreement with the virtual test predictions. This study highlights the importance of length-scale specific testing to minimize the influence of size effect on the transverse composite strength.
-
more » « less
Abstract The inferior water vapor permeability and water resistance properties are the major challenges that hindered the development of chitosan‐CNF composites for packaging applications. In this study, the chitosan‐CNF composite films were prepared with in situ crosslinking of citric acid (CA) to reduce the percent water uptake (WU) and water vapor permeability (WVP). The composite films were produced by the solvent casting method with 10%, 15%, and 20% CNF as a reinforcement, 20%, 25%, and 30% CA as a crosslinker, and 20% glycerol as a plasticizer. The Fourier transform infrared (FTIR) spectra of composite films with a peak at 1710 cm−1confirmed the effective crosslinking of citric acid on the chitosan‐CNF matrix. The crosslinked composite films exhibited the lowest WU of 39% and WVP of 9.99 × 10−7g/Pa s m2with reduced light transmittance due to CNF reinforcement. The scanning electron microscopy (SEM) study showed the smooth surface morphology of composite films. The CA crosslinking slightly decreased the tensile strength of composite films. However, the composite film with optimal CNF and CA concentration (25% and 20%, respectively) exhibited comparable tensile strength with other synthetic and biopolymer composites and can be used as a potential biopolymer composite for packaging applications.
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Journal Article:
- https://doi.org/10.3390/ma12142256
