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Title: Charge transfer and slow magnetic relaxation in a series of cyano-bridged FeIII4MII2 (M = Fe II , Co II , Ni II ) molecules
The synthesis, single-crystal structures and magnetic properties of three new cyano-bridged complexes [FeIII4MII2] (M = Fe II , Co II , Ni II ) are reported. Electronic absorption spectroscopy reveals the occurrence of intervalence charge transfer for [FeIII4FeII2]. Field-induced slow magnetic relaxation behavior is exhibited for [FeIII4CoII2] and [FeIII4NiII2] which originates from the ferromagnetic interactions between Fe III and M II spin centers of the square.  more » « less
Award ID(s):
1808779
NSF-PAR ID:
10108459
Author(s) / Creator(s):
; ; ; ;
Date Published:
Journal Name:
Inorganic Chemistry Frontiers
Volume:
6
Issue:
2
ISSN:
2052-1553
Page Range / eLocation ID:
493 to 497
Format(s):
Medium: X
Sponsoring Org:
National Science Foundation
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