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1. RTD Light Emission around 1550 nm with IQE up to 6% at 300 K

   https://doi.org/10.1109/DRC50226.2020.9135175  

   Brown, E. R. ; Zhang, W-D. ; Fakhimi, P. ; Growden, T. A. ; Berger, P.R. ( June 2020 , IEEE Device Research Conference (DRC), Columbus, OH (June 22-24, 2020))

   Resonant tunneling diodes (RTDs) have come full-circle in the past 10 years after their demonstration in the early 1990s as the fastest room-temperature semiconductor oscillator, displaying experimental results up to 712 GHz and fmax values exceeding 1.0 THz [1]. Now the RTD is once again the preeminent electronic oscillator above 1.0 THz and is being implemented as a coherent source [2] and a self-oscillating mixer [3], amongst other applications. This paper concerns RTD electroluminescence – an effect that has been studied very little in the past 30+ years of RTD development, and not at room temperature. We present experiments and modeling of an n-type In0.53Ga0.47As/AlAs double-barrier RTD operating as a cross-gap light emitter at ~300K. The MBE-growth stack is shown in Fig. 1(a). A 15-μm-diam-mesa device was defined by standard planar processing including a top annular ohmic contact with a 5-μm-diam pinhole in the center to couple out enough of the internal emission for accurate free-space power measurements [4]. The emission spectra have the behavior displayed in Fig. 1(b), parameterized by bias voltage (VB). The long wavelength emission edge is at  = 1684 nm - close to the In0.53Ga0.47As bandgap energy of Ug ≈ 0.75 eV at 300 K. The spectral peaks for VB = 2.8 and 3.0 V both occur around  = 1550 nm (h = 0.75 eV), so blue-shifted relative to the peak of the “ideal”, bulk InGaAs emission spectrum shown in Fig. 1(b) [5]. These results are consistent with the model displayed in Fig. 1(c), whereby the broad emission peak is attributed to the radiative recombination between electrons accumulated on the emitter side, and holes generated on the emitter side by interband tunneling with current density Jinter. The blue-shifted main peak is attributed to the quantum-size effect on the emitter side, which creates a radiative recombination rate RN,2 comparable to the band-edge cross-gap rate RN,1. Further support for this model is provided by the shorter wavelength and weaker emission peak shown in Fig. 1(b) around = 1148 nm. Our quantum mechanical calculations attribute this to radiative recombination RR,3 in the RTD quantum well between the electron ground-state level E1,e, and the hole level E1,h. To further test the model and estimate quantum efficiencies, we conducted optical power measurements using a large-area Ge photodiode located ≈3 mm away from the RTD pinhole, and having spectral response between 800 and 1800 nm with a peak responsivity of ≈0.85 A/W at  =1550 nm. Simultaneous I-V and L-V plots were obtained and are plotted in Fig. 2(a) with positive bias on the top contact (emitter on the bottom). The I-V curve displays a pronounced NDR region having a current peak-to-valley current ratio of 10.7 (typical for In0.53Ga0.47As RTDs). The external quantum efficiency (EQE) was calculated from EQE = e∙IP/(∙IE∙h) where IP is the photodiode dc current and IE the RTD current. The plot of EQE is shown in Fig. 2(b) where we see a very rapid rise with VB, but a maximum value (at VB= 3.0 V) of only ≈2×10-5. To extract the internal quantum efficiency (IQE), we use the expression EQE= c ∙i ∙r ≡ c∙IQE where ci, and r are the optical-coupling, electrical-injection, and radiative recombination efficiencies, respectively [6]. Our separate optical calculations yield c≈3.4×10-4 (limited primarily by the small pinhole) from which we obtain the curve of IQE plotted in Fig. 2(b) (right-hand scale). The maximum value of IQE (again at VB = 3.0 V) is 6.0%. From the implicit definition of IQE in terms of i and r given above, and the fact that the recombination efficiency in In0.53Ga0.47As is likely limited by Auger scattering, this result for IQE suggests that i might be significantly high. To estimate i, we have used the experimental total current of Fig. 2(a), the Kane two-band model of interband tunneling [7] computed in conjunction with a solution to Poisson’s equation across the entire structure, and a rate-equation model of Auger recombination on the emitter side [6] assuming a free-electron density of 2×1018 cm3. We focus on the high-bias regime above VB = 2.5 V of Fig. 2(a) where most of the interband tunneling should occur in the depletion region on the collector side [Jinter,2 in Fig. 1(c)]. And because of the high-quality of the InGaAs/AlAs heterostructure (very few traps or deep levels), most of the holes should reach the emitter side by some combination of drift, diffusion, and tunneling through the valence-band double barriers (Type-I offset) between InGaAs and AlAs. The computed interband current density Jinter is shown in Fig. 3(a) along with the total current density Jtot. At the maximum Jinter (at VB=3.0 V) of 7.4×102 A/cm2, we get i = Jinter/Jtot = 0.18, which is surprisingly high considering there is no p-type doping in the device. When combined with the Auger-limited r of 0.41 and c ≈ 3.4×10-4, we find a model value of IQE = 7.4% in good agreement with experiment. This leads to the model values for EQE plotted in Fig. 2(b) - also in good agreement with experiment. Finally, we address the high Jinter and consider a possible universal nature of the light-emission mechanism. Fig. 3(b) shows the tunneling probability T according to the Kane two-band model in the three materials, In0.53Ga0.47As, GaAs, and GaN, following our observation of a similar electroluminescence mechanism in GaN/AlN RTDs (due to strong polarization field of wurtzite structures) [8]. The expression is Tinter = (2/9)∙exp[(-2 ∙Ug 2 ∙me)/(2h∙P∙E)], where Ug is the bandgap energy, P is the valence-to-conduction-band momentum matrix element, and E is the electric field. Values for the highest calculated internal E fields for the InGaAs and GaN are also shown, indicating that Tinter in those structures approaches values of ~10-5. As shown, a GaAs RTD would require an internal field of ~6×105 V/cm, which is rarely realized in standard GaAs RTDs, perhaps explaining why there have been few if any reports of room-temperature electroluminescence in the GaAs devices. [1] E.R. Brown,et al., Appl. Phys. Lett., vol. 58, 2291, 1991. [5] S. Sze, Physics of Semiconductor Devices, 2nd Ed. 12.2.1 (Wiley, 1981). [2] M. Feiginov et al., Appl. Phys. Lett., 99, 233506, 2011. [6] L. Coldren, Diode Lasers and Photonic Integrated Circuits, (Wiley, 1995). [3] Y. Nishida et al., Nature Sci. Reports, 9, 18125, 2019. [7] E.O. Kane, J. of Appl. Phy 32, 83 (1961). [4] P. Fakhimi, et al., 2019 DRC Conference Digest. [8] T. Growden, et al., Nature Light: Science & Applications 7, 17150 (2018). [5] S. Sze, Physics of Semiconductor Devices, 2nd Ed. 12.2.1 (Wiley, 1981). [6] L. Coldren, Diode Lasers and Photonic Integrated Circuits, (Wiley, 1995). [7] E.O. Kane, J. of Appl. Phy 32, 83 (1961). [8] T. Growden, et al., Nature Light: Science & Applications 7, 17150 (2018). 

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2. Lack of Debye and Meissner screening in strongly magnetized quark matter at intermediate densities

   https://doi.org/https://doi.org/10.1103/PhysRevD.101.056012  

   B. Feng, E. J. ( March 2020 , Physical review)

   We study the static responses of cold quark matter in the intermediate baryonic density region(characterized by a chemical potentialμ) in the presence of a strong-magnetic field. We consider inparticular, the so-called magnetic dual Chiral Density Wave (MDCDW) phase, which is materialized by aninhomogeneous condensate formed by a particle-hole pair. It is shown, that the MDCDW phase is morestable in the weak-coupling regime than the one considered in the magnetic catalysis of chiral symmetrybraking phenomenon and even than the chiral symmetric phase that was expected to be realized atsufficiently high baryonic chemical potential. The different components of the photon polarization operatorof the MDCDW phase in the one-loop approximation are calculated. We found that in the MDCDW phasethere is neither Debye screening nor Meissner effect in the lowest-Landau-level approximation. Theobtained Debye length depends on the amplitudemand modulationbof the inhomogeneous condensateand it is only different from zero if the relation |μ−b|>m holds. But, we found that in the region ofinterest this inequality is not satisfied. Thus, no Debye screening takes place under those conditions. On theother hand, since the particle-hole condensate is electrically neutral, the U(1) electromagnetic group is notbroken by the ground state and consequently there is no Meissner effect. These results can be of interest forthe astrophysics of neutron stars 

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3. Cosmic ray protons and electrons from supernova remnants

   https://doi.org/10.1051/0004-6361/202140448  

   Cristofari, P. ; Blasi, P. ; Caprioli, D. ( June 2021 , Astronomy & Astrophysics)

   null (Ed.)

   Context. The spectrum of cosmic ray protons and electrons released by supernova remnants throughout their evolution is poorly known because of the difficulty in accounting for particle escape and confinement downstream of a shock front, where both adiabatic and radiative losses are present. Since electrons lose energy mainly through synchrotron losses, it is natural to ask whether the spectrum released into the interstellar medium may be different from that of their hadronic counterpart. Independent studies of cosmic ray transport through the Galaxy require that the source spectrum of electrons and protons be very different. Therefore, the above question acquires a phenomenological relevance. Aims. Here we calculate the spectrum of cosmic ray protons released during the evolution of supernovae of different types, accounting for the escape from the upstream region and for adiabatic losses of particles advected downstream of the shock and liberated at later times. The same calculation is carried out for electrons, where in addition to adiabatic losses we take the radiative losses suffered behind the shock into account. These electrons are dominated by synchrotron losses in the magnetic field, which most likely is self-generated by cosmic rays accelerated at the shock. Methods. We use standard temporal evolution relations for supernova shocks expanding in different types of interstellar media together with an analytic description of particle acceleration and magnetic field amplification to determine the density and spectrum of cosmic ray particles. Their evolution in time is derived by numerically solving the equation describing advection with adiabatic and radiative losses for electrons and protons. The flux from particles continuously escaping the supernova remnants is also accounted for. Results. The magnetic field in the post-shock region is calculated by using an analytic treatment of the magnetic field amplification due to nonresonant and resonant streaming instability and their saturation. The resulting field is compared with the available set of observational results concerning the dependence of the magnetic field strength upon shock velocity. We find that when the field is the result of the growth of the cosmic-ray-driven nonresonant instability alone, the spectrum of electrons and protons released by a supernova remnant are indeed different; however, such a difference becomes appreciable only at energies ≳100−1000 GeV, while observations of the electron spectrum require such a difference to be present at energies as low as ∼10 GeV. An effect at such low energies requires substantial magnetic field amplification in the late stages of supernova remnant evolution (shock velocity ≪1000 km s −1 ); this may not be due to streaming instability but rather hydrodynamical processes. We comment on the feasibility of such conditions and speculate on the possibility that the difference in spectral shape between electrons and protons may reflect either some unknown acceleration effect or additional energy losses in cocoons around the sources. 

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4. Comparison of quasi-geostrophic, hybrid and 3-D models of planetary core convection

   https://doi.org/10.1093/gji/ggac141  

   Barrois, O. ; Gastine, T. ; Finlay, C. C. ( April 2022 , Geophysical Journal International)

   We present investigations of rapidly rotating convection in a thick spherical shell geometry relevant to planetary cores, comparing results from quasi-geostrophic (QG), 3-D and hybrid QG-3D models. The 170 reported calculations span Ekman numbers, Ek, between 10−4 and 10−10, Rayleigh numbers, Ra, between 2 and 150 times supercritical and Prandtl numbers, Pr, between 10 and 10−2. The default boundary conditions are no-slip at both the ICB and the CMB for the velocity field, with fixed temperatures at the ICB and the CMB. Cases driven by both homogeneous and inhomogeneous CMB heat flux patterns are also explored, the latter including lateral variations, as measured by Q*, the peak-to-peak amplitude of the pattern divided by its mean, taking values up to 5. The QG model is based on the open-source pizza code. We extend this in a hybrid approach to include the temperature field on a 3-D grid. In general, we find convection is dominated by zonal jets at mid-depths in the shell, with thermal Rossby waves prominent close to the outer boundary when the driving is weaker. For the thick spherical shell geometry studied here the hybrid method is best suited for studying convection at modest forcing, $Ra \le 10 \, Ra_c$ when Pr = 1, and departs from the 3-D model results at higher Ra, displaying systematically lower heat transport characterized by lower Nusselt and Reynolds numbers. We find that the lack of equatorially-antisymmetric motions and z-correlations between temperature and velocity in the buoyancy force contributes to the weaker flows in the hybrid formulation. On the other hand, the QG models yield broadly similar results to the 3-D models, for the specific aspect ratio and range of Rayleigh numbers explored here. We cannot point to major disagreements between these two data sets at Pr ≥ 0.1, with the QG model effectively more strongly driven than the hybrid case due to its cylindrically averaged thermal boundary conditions. When Pr is decreased, the range of agreement between the hybrid and 3-D models expands, for example up to $Ra \le 15 \, Ra_c$ at Pr = 0.1, indicating the hybrid method may be better suited to study convection in the low Pr regime. We thus observe a transition between two regimes: (i) at Pr ≥ 0.1 the QG and 3-D models agree in the studied range of Ra/Rac while the hybrid model fails when $Ra\gt 15\, Ra_c$ and (ii) at Pr = 0.01 the QG and 3-D models disagree for $Ra\gt 10\, Ra_c$ while the hybrid and 3-D models agree fairly well up to $Ra \sim 20\, Ra_c$. Models that include laterally varying heat flux at the outer boundary reproduce regional convection patterns that compare well with those found in similarly forced 3-D models. Previously proposed scaling laws for rapidly rotating convection are tested; our simulations are overall well described by a triple balance between Coriolis, inertia and Archimedean forces with the length-scale of the convection following the diffusion-free Rhines-scaling. The magnitude of Pr affects the number and the size of the jets with larger structures obtained at lower Pr. Higher velocities and lower heat transport are seen on decreasing Pr with the scaling behaviour of the convective velocity displaying a strong dependence on Pr. This study is an intermediate step towards a hybrid model of core convection also including 3-D magnetic effects.

    

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5. Quantum electronic control on chemical activation of methane by collision with spin–orbit state selected vanadium cation

   https://doi.org/10.1039/D0CP04333H  

   Ng, Cheuk-Yiu ; Xu, Yuntao ; Chang, Yih-Chung ; Wannenmacher, Anna ; Parziale, Matthew ; Armentrout, P. B. ( January 2021 , Physical Chemistry Chemical Physics)

   null (Ed.)

   By coupling a newly developed quantum-electronic-state-selected supersonically cooled vanadium cation (V + ) beam source with a double quadrupole-double octopole (DQDO) ion–molecule reaction apparatus, we have investigated detailed absolute integral cross sections ( σ 's) for the reactions, V + [a 5 D J ( J = 0, 2), a 5 F J ( J = 1, 2), and a 3 F J ( J = 2, 3)] + CH 4 , covering the center-of-mass collision energy range of E cm = 0.1–10.0 eV. Three product channels, VH + + CH 3 , VCH 2 + + H 2 , and VCH 3 + + H, are unambiguously identified based on E cm -threshold measurements. No J -dependences for the σ curves ( σ versus E cm plots) of individual electronic states are discernible, which may indicate that the spin–orbit coupling is weak and has little effect on chemical reactivity. For all three product channels, the maximum σ values for the triplet a 3 F J state [ σ (a 3 F J )] are found to be more than ten times larger than those for the quintet σ (a 5 D J ) and σ (a 5 F J ) states, showing that a reaction mechanism favoring the conservation of total electron spin. Without performing a detailed theoretical study, we have tentatively interpreted that a weak quintet-to-triplet spin crossing is operative for the activation reaction. The σ (a 5 D 0 , a 5 F 1 , and a 3 F 2) measurements for the VH + , VCH 2 + , and VCH 3 + product ion channels along with accounting of the kinetic energy distribution due to the thermal broadening effect for CH 4 have allowed the determination of the 0 K bond dissociation energies: D 0 (V + –H) = 2.02 (0.05) eV, D 0 (V + –CH 2 ) = 3.40 (0.07) eV, and D 0 (V + –CH 3 ) = 2.07 (0.09) eV. Detailed branching ratios of product ion channels for the titled reaction have also been reported. Excellent simulations of the σ curves obtained previously for V + generated by surface ionization at 1800–2200 K can be achieved by the linear combination of the σ (a 5 D J , a 5 F J , and a 3 F J ) curves weighted by the corresponding Boltzmann populations of the electronic states. In addition to serving as a strong validation of the thermal equilibrium assumption for the populations of the V + electronic states in the hot filament ionization source, the agreement between these results also confirmed that the V + (a 5 D J , a 5 F J , and a 3 F J ) states prepared in this experiment are in single spin–orbit states with 100% purity. 

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