Carbon fiber-based structural lithium-ion batteries are attracting significant attention in the automotive and aerospace industries due to their dual capability of energy storage and mechanical load-bearing, leading to weight reduction. These batteries utilize lightweight carbon fiber (CF) composites, which offer excellent stiffness, strength-to-weight ratios, and electrical conductivity. Polyacrylonitrile-based CFs, comprising graphitic and amorphous carbon, are particularly suitable for Li-ion battery applications as they allow the storage of lithium ions. However, integrating lithium iron phosphate (LFP) into CFs poses challenges due to complex lab-scale processes and the use of toxic dispersants, hindering large-scale industrial compatibility. To address this, we investigate the development of water-based LFP-integrated CF structural Li-ion batteries. Homogeneous suspensions are created using cellulose nanocrystals (CNCs) to form hybrid structures. The battery system employs LFP-modified CF as the cathode, unsized CF as the anode, and a water-based electrolyte. The LFP-CNC-graphene nanoplatelet (GNP) hybrids are coated onto CFs through immersion coating. Scanning electron microscopy (SEM) images confirm the well-dispersed and well-adhered LFP-CNC-GNP structures on the CF surface, contributing to their mechanical interlocking and electrochemical performance. The batteries demonstrate a specific energy density of 62.67 Wh/kg and a specific capacity of 72.7 mAh/g. Furthermore, the cyclic voltammetry experiments reveal the stability of the LFP-CNC-GNP-coated CF batteries over 200 cycles without degradation. This research enables the engineering of hybrid nanostructured battery laminates using novel LFP-CNC-GNP-coated CFs, opening avenues for the development of innovative Li-ion structural batteries.
more »
« less
Nonlinear Observer and Simplified Equivalent Circuit Model-based EKF-SOC Estimator of a Rechargeable LiFePo4 cell
The lithium iron phosphate (LFP) battery has more nonlinear characteristic than other battery type. For this reason, when we use electrical equivalent circuit model and the extended Kalman filter (EKF) for estimating the SOC, the estimation performance can be decreased in the nonlinear region. This paper proposes an advance estimation method of state of charge (SOC) for lithium iron phosphate (LFP) batteries. To improve the model accuracy, this paper utilizes the nonlinear observer for identifying the internal parameters of batteries. Furthermore, to reduce the nonlinear effect of the LFP batteries, this paper recast the Kalman process. Therefore, through the proposed method, the performance of SOC estimation can be more accurate and the computational burden is decreased when we apply the embedded system.
more »
« less
- Award ID(s):
- 1816197
- NSF-PAR ID:
- 10109881
- Date Published:
- Journal Name:
- IEEE ICPE 2019 conference in Busan, Korea
- Page Range / eLocation ID:
- 2610-2614
- Format(s):
- Medium: X
- Sponsoring Org:
- National Science Foundation
More Like this
-
-
more » « less
This article focuses on state‐of‐charge (SOC) estimation in a lithium‐ion battery, using measurements of terminal voltage and bulk force. A nonlinear observer designed using Lyapunov analysis relying on lower and upper bounds of the Jacobian of the nonlinear output function is utilized. Rigorous analysis shows that the proposed observer has feasible design solutions only in each piecewise monotonic region of the output functions and has no constant stabilizing observer gain when the entire SOC range is considered. The nonmonotonicity challenge is then addressed by designing a hybrid nonlinear observer that switches between several constant observer gains. The global stability of the switched system is guaranteed by ensuring overlap between regions and an adequate dwell time between switches. The performance of the observer is evaluated first through simulations using a high‐fidelity battery model and then through experiments. The performance of the nonlinear observer is compared with that of an extended Kalman Filter. Simulation results show that with no model uncertainty the nonlinear observer provides estimates with an RMS error of 1.1%, while the EKF performs better, providing an RMS error less than 1%. However, when model error is introduced into this nonmonotonic system, the EKF becomes unstable for even very small model errors in the output curves. The nonlinear observer, on the other hand, continues to perform very well, providing accurate estimates and never becoming unstable. The experimental results verify the observations from the simulation and the experimental EKF is found to become unstable due to model errors, while the hybrid nonlinear observer continues to work reliably.
-
Dendritic growth of lithium (Li) is hindering potential applications of Li-metal batteries, and new approaches are needed to address this challenge. The confinement effect of two-dimensional materials triggered by strong molecular interactions between parallelly-aligned graphene oxide (GO) at Li metal interface is proposed here as a new strategy to suppress the dendritic growth of Li. The effectiveness of aligned GO for Li-metal cells is shown for two different polymer separator cells:liquid electrolytes with porous propylene (PP) separators and solid polyethylene oxide (PEO) electrolytes. For the case of liquid electrolytes, PP separators were modified with plasma treatment to induce the alignment of GO layers. The Li‖Li cells with aligned GO illustrate a stable Li platting/stripping (up to 1000 cycles). The Li‖lithium iron phosphate (LFP) battery cells with aligned GO could cycle at 5C for 1000 cycles (∼90% capacity retention). For solid polymer electrolyte (SPE) cells, GO–Li confinement effect is also effective in Li dendrites suppression enhancing the stability and lifespan of Li-metal batteries. The Li‖LFP cell with the GO-modified SPE showed ∼85% capacity retention after 200 cycles at 1C. Such combined high rate capability and number of cycles exceeds the previously reported performances for both liquid and SPE-based Li‖LFP cells. This points to a new opportunity for utilizing the confinement effect of two-dimensional materials for the development of next generation, fast rate rechargeable Li batteries.more » « less
-
more » « less
Switching from organic to aqueous solvents for battery electrode processing is desirable due to both safety and cost advantages. Lithium iron phosphate (LFP) is considered a cathode material for aqueous processing due to its demonstrated chemical compatibility with water, in addition to its favorable cost, safety, electrochemical performance, and environmental advantages as a battery active material. All research on LFP stability in water has been conducted in a scenario where LFP is aged in stagnant water, or surrounded by water when confined within a composite electrode. However, a much accelerated degradation in the electrochemical performance of LFP when it is in contact with water and exposed to mechanical agitation is demonstrated. Changes to LFP are probed using a combination of materials characterization methods. Although there are no significant changes to the bulk particle structure and morphology, significant particle surface damage and compositional modifications are observed. These results suggest that the systems where LFP is exposed to agitation in an aqueous environment, such as in aqueous battery electrode processing or in aqueous slurry electrodes, need to be carefully investigated for potential changes to the LFP surface environment under relevant processing conditions.
-
more » « less
Abstract NASICON‐type sodium vanadium phosphate (Na3V2(PO4)3, or NVP) cathode materials have great potential for fast charging and long cycling sodium‐ion batteries (SIBs) similar to lithium iron phosphate (LiFePO4, or LFP) cathode materials used in lithium‐ion batteries (LIBs). However, the cycle life and energy density in the full cell using NVP materials need to be significantly improved. This paper investigates the degradation mechanisms of NVP‐based SIBs and identifies the Na loss from the cathode to the anode solid electrolyte interphase (SEI) reactions as the main cause of capacity degradation. A new Na‐rich NVP cathode (e.g., Na4V2(PO4)3, or Na4VP) is developed to address the Na loss problem. Conventional NVP can be easily transformed into the Na4VP by a facile and fast chemical solution treatment (30 s). Na‐free‐anode Na4VP and hard carbon‐Na4VP full cells are assembled to evaluate the electrochemical properties of the Na‐rich NVP cathode. The Na4VP cathode provides excess Na to compensate for the Na loss, resulting much longer cycle life in the full cells (>400 cycles) and a high specific energy and power density. Good low‐temperature performance is also observed.
- Free Publicly Accessible Full Text
-
Accepted Manuscript1.0
- Conference Paper:
- The DOI is not currently available.
